Vegetable samples of brinjal, okra, green chilli, crucifers, and cucurbits collected from farmers' field were tested for the presence of organochlorine (OC), organophosphorus (OP), and synthetic pyrethroid (SP) compounds using a gas chromatograph equipped with electron capture and flame thermionic detectors. Of the samples tested, 34.0% were found to have pesticide residues. Among the OC compounds, α-endosulfan, β-endosulfan, and endosulfan sulfate were detected in 14.5% of the samples with residues. These were taken from crucifer, okra, green chilli, and cucurbit samples. SP compound residues, such as α-cypermethrin, fenvalerate I, fluvalinate I, deltamethrin, and λ-cyhalothrin were detected in 32% of the samples with residues. OP compound residues such as chlorpyrifos, profenofos, monocrotophos, triazophos, ethion, dimethoate, and acephate were found in 54% of the samples with residues, which were taken from all vegetable samples. Of the positive samples, 15.3% were found to contain residues exceeding the prescribed maximum residue limit. The average pesticide residue content across all the vegetable samples was 0.108 ppm, with values ranging from 0.008 to 2.099 ppm. Multiple residues of more than one compound were detected in 34.1% of samples containing residues.

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Study of nitrogen release pattern from organic manures is very essential to ensure nitrogen supply in adequate quantity and at proper time to crop plants in an acid soil. A laboratory incubation experiment was conducted to determine the nitrogen release pattern from vermicompost (V.C), poultry manure (P.M), neem, inorganic fertilizer (I.O) and its combinations applied to an acid soil at two different rates. Cumulative nitrogen mineralization was significantly higher throughout the incubation period for I.O, V.C+P.M and I.O+V.C while it was two weeks after incubation for V.C and V.C+Neem due to the inhibitory effect of neem on nitrification. The results indicated a significant increase in the rate of N mineralization in the first one week in which the highest rate of 3.36 mg N day -1 was observed for inorganic fertilizer and thereafter it slowed down. V.C followed by V.C+Neem recorded higher rate of N mineralization of 0.24 and 0.23 mg day -1 respectively, from 48 th days after incubation. V.C+Neem at 120 kg N equivalent ha -1 recorded the highest ammonia content of 42.1% to total available N while V.C+P.M recorded higher nitrate content of 82.3% at the end of the incubation period. Positive correlation between initial nitrogen and total mineralized N from the manures and fertilizers (R 2 = 0.563) was observed. Furthermore, addition of organic manures resulted in increase in soil pH where as inorganic fertilizer showed a slight decrease (5.73) than control (5.78).

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Pesticides are shown to have a great effect on soil organisms, but the effect varies with pesticide group and concentration, and is modified by soil organic carbon content and soil texture. In the humid tropical islands of Andaman, India, no systematic study was carried out on pesticide residues in soils of different land uses. The present study used the modified QuEChERS method for multiresidue extraction from soils and detection with a gas chromatograph. DDT and its various metabolites, α-endosulfan, β-endosulfan, endosulfan sulfate, aldrin, and fenvalerate, were detected from the study area. Among the different pesticide groups detected, endosulfan and DDT accounted for 41.7 % each followed by aldrin (16.7 %) and synthetic pyrethroid (8.3 %). A significantly higher concentration of pesticide residues was detected in rice-vegetable grown in the valley followed by rice-fallow and vegetable-fallow in the coastal plains. Soil microbial biomass carbon is negatively correlated with the total pesticide residues in soils, and it varied from 181.2 to 350.6 mg kg(-1). Pesticide residues have adversely affected the soil microbial populations, more significantly the bacterial population. The Azotobacter population has decreased to the extent of 51.8 % while actinomycetes were the least affected though accounted for 32 % when compared to the soils with no residue.