SO9 5NH)Summary Octadienyl and butenyl substituted amines reported. Tertiary phosphine complexes of palladium(0) have been shown to catalyse the reaction of buta-1,3-diene with methanol and phenol to give l-methoxyocta-2,7-diene and l-phenoxyocta-2,7-diene, respective1y.l Similar reactions have been demonstrated with primary and secondary A NUMBER of palladium complex-catalysed reactions of amines, carboxylic acids,2 9 3 and active-methylene and active-hydrogen compounds with buta-1,3-diene have been -methine compounds.4 have been prepared by reaction of primary and secondary amines with butadiene catalysed by nickel( 0) complexes.
Die Umsetzung von Morpholin (Ia), Di‐n‐propylamin (Ib) und Benzyl‐methylketon (Ic) mit Butadien (II) in Gegenwart von Nickelbromid und (VII) oder Nickelacetylacetonat (VIII) und (VII) ergibt die Verbindungen (III)‐(VI).
Butadien (I) reagiert mit Morpholin (IIa) oder Di‐n‐propylamin (IIb) in Gegenwart von Nicke1acetylacetonat, Phenyldiisopropoxyphosphin und Natriumborhydrid bei 100°C zu den N‐Butenyl‐Derivaten (III) und (IV) sowie zu den N‐Octadienyl‐Derivaten (V) und (VI).
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