Linen fibres were coated with a glow‐in‐the‐dark photoluminescence, flame‐retarding, and hydrophobic smart nanocomposite using the pad‐dry‐curing process. Ecologically friendly ammonium polyphosphate and lanthanide‐activated strontium aluminium oxide (LSAO) nanoparticles were immobilized into linen fabric using eco‐friendly room‐temperature‐vulcanizing silicone rubber. Different analytical techniques were used to examine the morphological characteristics and elemental compositions of LSAO nanoparticles and treated linen textiles. The self‐extinguishing properties of the treated linen textiles were tested for their fire resistance. After 24 washing cycles, the coated linen samples retained their flame‐retarding properties. The treated linen's superhydrophobicity rose in direct proportion to the LSAO concentration. After being excited at 365 nm, the colourless luminescent film that was coated on linen surface gave out an emission wavelength of 519 nm. The photoluminescent linen was monitored to create a range of different colours, including off‐white in daytime light and green under ultraviolet (UV) light radiation, according to the Commission Internationale de l'éclairage laboratory colorimetric coordinates and photoluminescence spectra. Emission, excitation, and lifetime spectral analysis of the treated linen revealed persistent phosphorescence. For mechanical and comfort evaluation, the coated linen textiles' bending length and air permeability were assessed. Good UV light shielding and enhanced antibacterial activity were detected in the treated linens.
Screen-printing and spray-coating methods were used to produce photoluminescent, water-repellent, and antimicrobial films on textile fibers. The cotton fabrics were firstly finished with a flame-resistant agent. There are a number of functional agents that have been applied during the textile finishing process, including strontium aluminate pigment as antibacterial and photoluminescent agent, flame-retardant organophosphate, and water-repellent silicone rubber. The current research investigated the surface morphologies and chemical compositions of the screen-printed and spray-coated fabric cottons using scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy-dispersive X-ray (EDX), wavelength dispersive X-ray fluorescence (WDXRF), and Fourier-transform infrared spectroscopy (FT-IR). According to morphological analysis, the phosphor nanoparticles had sizes ranging from 2 to 12 nm. After excitation at 399 nm, the generated colorless photoluminescent layer deposited onto cotton surface showed an emission profile at 516 nm. The luminescence spectra and CIE Lab characteristics confirmed that the phosphor-coated textiles displayed a white color in visible spectrum and green emission in the presence of UV light. It has been shown by analysis that the tested colors are very stable over time. The measurements of static water contact and sliding angles were also explored. The self-extinguishing activity of the coated fabrics retained their flame-retardant properties over 24 laundry cycles. Antimicrobial activity, hydrophobicity, and luminous properties were improved without affecting the intrinsic physical and mechanical features of the treated textiles. Details on the CIE Lab colorimetric measurements were discussed. The stiffness and air permeability were examined to explore the flexibility and breathability of the treated textile fibers. Excellent reversibility and photostability were seen in the phosphor-coated materials.
The present work discusses the possibility of applying enzymatic treatments for fabric surface activation that can facilitate the loading of zinc oxide nanoparticles (ZnO NPs) onto polyester (PET) and polyester cotton blend (PET/C) fabrics prepared by sol-gel method. Activated polyester fabrics loaded by ZnO NPs were investigated by the use of scanning electron microscopy (SEM), electron dispersion emission X-ray (EDX) and Fourier transformed infrared spectroscopy (FT-IR). The functionality of activated polyester fabrics loaded by ZnO NPs was evaluated by analyzing its antimicrobial activity and UV protection efficiency. Antimicrobial activity of activated polyester fabrics and loaded by ZnO NPs was tested against Gram-positive (Bacillus mycoides), Gram-negative (Escherichia coli), and nonfilamentous fungus (Candida albicans). The level of UV protection was verified by the UV protection factor (UPF) of polyester fabrics. Activated post-treated polyester fabrics exhibited outstanding antimicrobial and UV protection efficiency. The achieved antimicrobial function and UV protection on the polyester fabrics are durable with repeated laundering processes even after five washing cycles.
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