Herein, results of combined greenhouse gas treatment with clean energy conversion is reported for the first time. Multi-channel tubular SOFCs were operated with N 2 O instead of air as the oxidant leading to a 50% increase in power density. Techno-economic evaluation suggested the feasibility of the combined approach eliminating the cost penalty for N 2 O abatement.
The severity of vapour cloud explosions is typically correlated with the peak over-pressure or, more accurately, with the total impulse caused by the pressure waves. The flame speed arising from strong (e.g. quasi-stable) turbulent deflagrations is frequently used to provide an indication of potential damage. However, conventional flame propagation mechanisms can present difficulties in terms of explaining the resulting damage. For example, the over-pressure in the Buncefield vapour cloud explosion was much higher than that predicted by conventional models. Alternative propagation mechanisms include intermittent localised strong explosions or detonations potentially supported by forward thermal radiation causing multi-point ignition of dust particles ahead of the advancing flame front. Such mechanisms are here explored using particles coated with acetylene black as the radiation target due to their relationship with soot emissions. A continuous wave laser operating in the near infrared was used as the radiation source with experiments performed in a flame tube using fuel lean CH 4 /H 2 /Air mixtures. It is shown that ignition kernels caused by irradiated particles can successfully be entrained into the main flow and/or recirculation zones formed around obstacles and cause multipoint explosions. The resulting relationship between fuel consumption ahead of the advancing flame and the evolution of the strength of the explosion is shown to be complex and typically lead to increased explosion durations with reduced peak pressures. It is also shown that chaotic pressure wave interactions can substantially increase both the explosion duration and the peak pressure depending on the timing of the radiation induced ignition.
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