The G-200 glass of the glass-ionomer cement has two phases: a continuous calcium aluminosilicate matrix and partly crystalline calcium fluoride-rich droplets, the nature of which depend on the thermal history of the glass. The setting process of the cement takes place when the glass is mixed with poly(acrylic acid). It has two overlapping stages corresponding to the rapid leaching of calcium ions from the uncrystalline part of the droplets, followed by the slower release of aluminum (and some calcium) from the main glass phase. These processes are affected by the microstructure and microcomposition of the glass.
MTDATA embodies the principle that equilibria in multicomponent, multiphase systems can be calculated from a knowledge of the thermodynamic data for the subsystems. A number of modules are incorporated for manipulating and retrieving the data, making various types of calculation and plotting binary, ternary, multicomponent, and predominance area diagrams. The principles and operation of MTDAT A are illustrated by reference to systems of practical importance.
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