Diesel exhaust particles are the major constituent of urban carbonaceous aerosol being linked to a large range of adverse environmental and health effects. In this work, the effects of fuel reformulation, oxidation catalyst, engine type, and engine operation parameters on diesel particle emission characteristics were investigated. Particle emissions from an indirect injection (IDI) and a direct injection (DI) engine car operating under steady-state conditions with a reformulated low-sulfur, low-aromatic fuel and a standard-grade fuel were analyzed. Organic (OC) and elemental (EC) carbon fractions of the particles were quantified by a thermal-optical transmission analysis method and particle size distributions measured with a scanning mobility particle sizer (SMPS). The particle volatility characteristics were studied with a configuration that consisted of a thermal desorption unit and an SMPS. In addition, the volatility of size-selected particles was determined with a tandem differential mobility analyzer technique. The reformulated fuel was found to produce 10-40% less particulate carbon mass compared to the standard fuel. On the basis of the carbon analysis, the organic carbon contributed 27-61% to the carbon mass of the IDI engine particle emissions, depending on the fuel and engine operation parameters. The fuel reformulation reduced the particulate organic carbon emissions by 10-55%. In the particles of the DI engine, the organic carbon contributed 14-26% to the total carbon emissions, the advanced engine technology, and the oxidation catalyst, thus reducing the OC/EC ratio of particles considerably. A relatively good consistency between the particulate organic fraction quantified with the thermal optical method and the volatile fraction measured with the thermal desorption unit and SMPS was found.

The effects of fuel and lubricating oil formulation and exhaust catalytic aftertreatment on physical and chemical characteristics of two-stroke engine exhaust particles were studied. The exhaust particles were produced with a professional chainsaw engine. The employed fuels were a 98-octane oxygenated, low-sulfur, low-aromatic reformulated gasoline, which served as a reference, and a 95-octane nonoxygenated alkylate gasoline that had no aromatics and olefins. The applied lubricating oils were a semisynthetic mineral-based oil and a biodegradable ester-based oil. In total eight fuel-lubricating oil-catalyst combinations were studied. The test runs were conducted on a test bench and exhaust was diluted in a full-flow dilution tunnel. The size and number emissions of the exhaust particles were measured with a scanning mobility particle sizer (SMPS). The organic carbon (OC) and elemental carbon (EC) composition of the particles were analyzed with a thermal-optical transmission analyzer (TOT). In addition, the inorganic ion and metal composition of the particles were quantified, and the gaseous total hydrocarbon (THC), carbon monoxide (CO), and nitrogen oxide (NOx) emissions were measured. The volatility characteristics of the exhaust particles were studied with a thermal desorption unit combined with the SMPS. The particle mass (PM) emissions ranged without catalyst from 2.9 to 3.4 g/kWh and with catalyst from 1.7 to 2.4 g/kWh, the catalytic converter thus reducing PM emissions by 19-50%. Without catalyst the alkylate fuel-biodegradable oil combination gave the highest particle mass emissions, but with catalyst with the same fuel-oil mixture the emissions were the lowest. The count median diameter (CMD) of the particles ranged from 57 to 123 nm. Without catalyst, the alkylate fuel-biodegradable oil combination gave the lowest number emissions, but with catalyst with the same fuel-oil combination the emissions were the highest. The catalytic converter reduced the particle size by 22-56 nm, but it also increased the number emissions by a factor of 1.3-2.6. In thermal analysis 88-98% of the exhaust particle volume proved to be volatile, the solid fraction consisting of elemental carbon and metal residues. With the mineral-based lubricating oil, the metal residues appeared in two modes at the evaporation temperatures of 350 • C and higher, while in the particles produced with the biodegradable oil the residues were unimodally distributed.

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