Rainfall and temperature variability causes changes in groundwater recharge that can also influence groundwater quality by different processes. The aim of this study is the analysis of the hydrogeochemical variations over time due to meteorological variability in two different study areas in Italy: an alluvial aquifer in the Piedmont Po plain and an alluvial-pyroclastic aquifer in the Campanian plain. The examined plains show groundwater with natural quality not satisfying the European drinking water standards, or anthropogenic contamination. The peculiar natural quality is due, in the Campanian plain, to the closeness of volcanic areas, and to the presence of reducing conditions. In Piedmont plain a test site is characterized by a point-source contamination by heavy metals, due to the presence of past industrial activities. In all the examined areas there is a diffuse nitrate contamination. The fluctuations of the ions As, F, Fe, Mn, Cr VI, NO3, and Cl were analyzed and compared, using statistical methods, with the variations over time in precipitation, temperature, and piezometric levels, sometimes significant. Results highlight the importance of the groundwater and meteorological monitoring and the key role of the recharge variation in the hydrogeochemical processes. The linking degree between rainfall/temperature variability and hydrogeochemistry is variable, in function of the typology of chemical species, their origin, and of the aquifer characteristics. The fluctuation of climate variables determines sudden changes in the geochemistry of shallow unconfined aquifers (e.g., in the Piedmont plain), while semiconfined or confined aquifers (e.g., in the Volturno-Regi Lagni plain) react with a greater delay to these variations. Moreover, natural quality is more affected by climatic variations than anthropogenic contamination, which is the result of multiple environmental and anthropic factors.
This paper represents the first regional-scale investigation in the Piedmont Po plain about the relationship between groundwater temperature (GWT) and climate variability. The understanding of relationships between air temperature (AT) and GWT is really important, especially in the context of global climate change. The aim of this investigation is to study the relationship between GWT and AT over a 10-year time period (from 2010 to 2019) to analyse how these two parameters interrelate and to evaluate possible trends. To carry out this study, basic statistic interpolations were performed on both parameters to facilitate comparison. Both AT and GWT showed an increase over the observed decade with a more pronounced growth of the AT; this allow to state that GWT is more resilient to climate change than AT. However, some areas in the Piedmont plain showed a behaviour that partially deviated from the standard trend observe for the majority of the region. These areas were influenced by particular anthropic factors (for example the paddy fields in the Novara plain) or natural elements (as the monitoring wells in the “Canavese” area, located downstream of melting glaciers, or the wells located close to the Tanaro River). Moreover, this study wanted to stress the importance of the knowledge of the localization in wells of the instruments for the GWT measurement, to have the most accurate and comparable data. It was proved that as the depth increased, the maximum and minimum peaks of the GWT shifted in time respect to the maximum and minimum peaks of the AT, and, in addition, the GWT fluctuation in the bottom part of the aquifer was milder than the fluctuation observed in the most superficial part. Further investigations will be conducted in future in Piedmont plain areas with different behavior, in order to better understand their dynamics and the factors that may influence GWT and how they are affected by climate change.
In the context of global climate change, understanding the relationships between climate and groundwater is increasingly important. This study in the NW Alps represents the first regional-scale investigation of the groundwater feature variation in mountain aquifers due to climate variability. The analysis of groundwater temperature and discharge in 28 natural mineral water springs and meteorological parameters (rainfall and air temperature) permitted us to evaluate the annual behaviour and possible trends of these parameters during the period from 2001 to 2018. The air temperature showed a positive trend almost everywhere, with a rise of up to 0.03 °C/year. In contrast, only ten springs showed a positive trend for groundwater temperature, but with the smallest rates of increase. Moreover, despite the substantial stability of the rainfall amount, 50% of the analysed springs showed a trend (29 and 21% for positive and negative trends, respectively) with low discharge variations. Finally, cross-correlation analyses proved the close relationship between air and groundwater temperatures, with a time lag between 0 and 3 months, and between spring discharge and air temperature, with a time lag between 1 and 3 months. In particular, spring discharge is closely connected to snow melting in spring and subordinate to rainfall. These results highlight the existing correlations between spring discharge and various meteorological and topographic parameters in the studied mountain area and provide a preliminary framework of the impacts of climatic variability on the availability and temperature of the exploited water resources.
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