Highlights
The life-threatening side effects of cancer treatment are addressed using nano-formulations and combinational therapy.
Herbal drugs displayed potency in curing cancer using a nanofiber based device.
Allopathic anti-cancer drugs can be delivered at a targeted site using a nanofiber based drug carrier which improves bioavailability to a great extent.
A combination of an herbal and allopathic anticancer drug could be a possible life-saving union to cure cancer.
One of the major constituents of heavy oil is asphaltenes.
They
are responsible for numerous problems in petroleum downstream and
upstream processes, such as catalyst deactivation in heavy oil processing
and blocking pipes while transporting crude oil. Probing the efficiency
of new nonhazardous solvents in separating asphaltenes from crude
oil is key to avoid conventional volatile and hazardous solvents by
replacing these conventional solvents with new ones. In this work,
we have investigated the efficiency of ionic liquids to separate asphaltenes
from organic solvents (such as toluene and hexane) using molecular
dynamics simulations. Triethylammonium-dihydrogen-phosphate and triethylammonium
acetate ionic liquids are considered in this work. Various structural
and dynamical properties are calculated, such as radial distribution
function, end-to-end distance, trajectory density contour, and diffusivity
of asphaltene in the ionic liquid-organic solvent mixture. Our results
explain the role of anions, i.e., dihydrogen-phosphate and acetate
ions, in separating asphaltene from toluene and hexane. Our study
provides an important revelation about the dominant role played by
the IL anion in intermolecular interactions which depends on the type
of solvent (i.e., toluene or hexane) in which the asphaltene is present.
The anion induces enhanced aggregation in the asphaltene-hexane mixture
compared to the asphaltene-toluene mixture. The molecular insights
obtained within this study on the role played by ionic liquid anion
in asphaltene separation are key for the preparation of new ionic
liquids for asphaltene precipitation applications.
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