In the face of water shortages, the world seeks to explore all available options in reducing the over exploitation of limited freshwater resources. One of the surest available water resources is wastewater. As the population grows, industrial, agricultural, and domestic activities increase accordingly in order to cater for the voluminous needs of man. These activities produce large volumes of wastewater from which water can be reclaimed to serve many purposes. Over the years, conventional wastewater treatment processes have succeeded to some extent in treating effluents for discharge purposes. However, improvements in wastewater treatment processes are necessary in order to make treated wastewater re-usable for industrial, agricultural, and domestic purposes. Membrane technology has emerged as a favorite choice for reclaiming water from different wastewater streams for re-use. This review looks at the trending membrane technologies in wastewater treatment, their advantages and disadvantages. It also discusses membrane fouling, membrane cleaning, and membrane modules. Finally, recommendations for future research pertaining to the application of membrane technology in wastewater treatment are made.
The coronavirus (COVID-19) pandemic is currently posing a significant threat to the world’s public health and social-economic growth. Despite the rigorous international lockdown and quarantine efforts, the rate of COVID-19 infectious cases remains exceptionally high. Notwithstanding, the end route of COVID-19, together with emerging contaminants’ (antibiotics, pharmaceuticals, nanoplastics, pesticide, etc.) occurrence in wastewater treatment plants (WWTPs), poses a great challenge in wastewater settings. Therefore, this paper seeks to review an inter-disciplinary and technological approach as a roadmap for the water and wastewater settings to help fight COVID-19 and future waves of pandemics. This study explored wastewater–based epidemiology (WBE) potential for detecting SARS-CoV-2 and its metabolites in wastewater settings. Furthermore, the prospects of integrating innovative and robust technologies such as magnetic nanotechnology, advanced oxidation process, biosensors, and membrane bioreactors into the WWTPs to augment the risk of COVID-19’s environmental impacts and improve water quality are discussed. In terms of the diagnostics of COVID-19, potential biosensors such as sample–answer chip-, paper- and nanomaterials-based biosensors are highlighted. In conclusion, sewage treatment systems, together with magnetic biosensor diagnostics and WBE, could be a possible way to keep a surveillance on the outbreak of COVID-19 in communities around the globe, thereby identifying hotspots and curbing the diagnostic costs of testing. Photocatalysis prospects are high to inactivate coronavirus, and therefore a focus on safe nanotechnology and bioengineering should be encouraged.
The photocatalytic degradation of a local South Africa oil refinery wastewater was conducted under UV radiation using an aqueous catalyst of titanium dioxide (TiO2), Degussa P25 (80% anatase, 20% rutile) in suspension. the experiment was carried out in a batch aerated photocatalytic reactor based on a central composite design (CCD) and analyzed using response surface methodology (RSM). The effects of three operational variables viz. TiO 2 dosage (2-8 g/L), runtime (30-90 minutes), and airflow rate (0.768-1.48 L/min) were examined for the removal of phenol and soap oil and grease (SOG). The data derived from the CCD, and the successive analysis of variance (ANOVA) showed the TiO 2 dosage to be the most influential factor, while the other factors were also significant (P < 0.0001). Also, the ANOVA test revealed the second-order of tio 2 dosage and runtime as the main interaction factors on the removal efficiency. To maximize the pollutant removal, the optimum conditions were found at runtime of 90 minutes, TiO 2 dosage of 8 g/L, and an aeration flow rate of 1.225 L/min. Under the conditions stated, the percentage removal of phenol (300 ± 7) and SOG (4000 ± 23) were 76% and 88% respectively. At 95% confidence level, the predicted models developed results were in reasonable agreement with that of the experimental data, which confirms the adaptability of the models. The first-order kinetic constants were estimated as 0.136 min −1 and 0.083 min −1 for SOG and phenol respectively. Photocatalysis has attracted worldwide interest due to its potential to use solar energy not only to solve environmental problems but also to provide renewable and sustainable energy 1,2. However, the ever-increasing demand for good water quality and oil refinery products have become expensive commodities with major challenges, which requires thoughtful attention 3,4. Oily waste from petroleum refinery has aliphatic and phenolic compounds, are considerably carcinogenic and toxic to the ecosystem and human health, and therefore their removal from wastewater is of global concern 3,5,6. The tox,icity and extreme instability of oily waste make them not degradable easily, this pose a significant threat to the water bodies and soil 5-7. Meanwhile, the processing of crude oil consumes large volumes of water and generates about 0.4-1.6 times the amount of crude oil processed as oil refinery wastewater (ORW) 8-10. The discharge of ORW with adequate or no treatment, due to their inertness, endocrine-disrupting abilities, and carcinogenic behaviour could also affect water bodies and soil profile negatively 9-11. Therefore, there is the need to develop sustainable and eco-effective methods to mitigate the oily pollutants from the ORW, to produce clean water and a sustainable environment 12. In this case, the photocatalysis technology was considered. Unfortunately, the production of polluted wastewater (ORW) is based on the raw crude oil type, plant configuration, and operational procedure, which varies in physicochemical parameters as compared to urban wa...
Advanced oxidation processes (AOPs) have many prospects in water and wastewater treatment. In recent years, AOPs are gaining attention as having potentials for the removal of different ranges of contaminants from industrial wastewater towards water reclamation. In this study, the treatability efficiencies of two photo-catalysts (TiO2 and zeolite) were compared on the basis of the removal of chemical oxygen demand (COD) and SO42− from oil refinery wastewater (ORW) using photo-catalytic system. The effects of three operating parameters: catalyst dosage (0.5–1.5 g/L), reaction time (15–45 min), mixing rate (30–90 rpm) and their interactive effects on the removal of the aforementioned contaminants were studied using the Box–Behnken design (BBD) of response surface methodology (RSM). Statistical models were developed and used to optimize the operating conditions. An 18 W UV light was incident on the system to excite the catalysts to trigger a reaction that led to the degradation and subsequent removal of contaminants. The results obtained showed that for almost the same desirability (92% for zeolite and 91% for TiO2), TiO2 exhibited more efficiency in terms of mixing rate and reaction time requirements. At the 95% confidence level, the model’s predicted results were in good agreement with experimental data obtained.
Conventionally, the anaerobic digestion of industrial effluent to biogas constitutes less than 65% methane, which warrants its potential methanation to mitigate carbon dioxide and other anthropogenic gas emissions. The performance of the anaerobic digestion process can be enhanced by improving biochemical activities. The aim of this study was to examine the synergistic effect of the magnetite and bioelectrochemical systems (BES) on anaerobic digestion by comparing four digesters, namely a microbial fuel cell (MFC), microbial electrolysis cell (MEC), MEC with 1 g of magnetite nanoparticles (MECM), and a control digester with only sewage sludge (500 mL) and inoculum (300 mL). The MFC digester was equipped with zinc and copper electrodes including a 100 Ω resistor, whereas the MEC was supplied with 0.4 V on the electrodes. The MECM digester performed better as it improved microbial activity, increased the content of methane (by 43% compared to 41% of the control), and reduced contaminants (carbon oxygen demand, phosphates, colour, turbidity, total suspended solids, and total organic carbon) by more than 81.9%. Current density (jmax = 25.0 mA/m2) and electrical conductivity (275 µS/cm) were also high. The prospects of combining magnetite and bioelectrochemical systems seem very promising as they showed a great possibility for use in bioelectrochemical methane generation and wastewater treatment.
Membrane technology has gained much ground in water and wastewater treatment over the past couple of decades. This is timely, as the world explores smart, eco-friendly, and cheap water and wastewater treatment technologies in its quest to make potable water and sanitation commonplace in all parts of the world. Against this background, this study investigated forward osmosis (FO) in the removal of salts (chlorides, sulphates, and carbonates) and organics (chemical oxygen demand (COD), turbidity, total suspended solids (TSS), and color) from a synthetic municipal wastewater (MWW), mimicking secondary-treated industrial wastewater, at very low feed and draw solution flow rates (0.16 and 0.14 L/min respectively), using 70 g/L NaCl solution as the draw solution. The results obtained showed an average of 97.67% rejection of SO42− and CO32− while Cl− was found to enrich the feed solution (FS). An average removal of 88.92% was achieved for the organics. A permeation flux of 5.06 L/m2.h was obtained. The kinetics of the ions transport was studied, and was found to fit the second-order kinetic model, with Pearson’s R-values of 0.998 and 0.974 for Cl− and CO32− respectively. The study proves FO as a potential technology to desalinate saline MWW.
This study focuses on the process optimization of coagulation floatation by cross-interaction effects of the following multiple factors: pH, coagulant dosage and floatation time on the response of chemical oxidation demand (COD), soap oil and grease (SOG), turbidity and total suspended solids (TSS). The results from the response surface methodology incorporated with Box Benken design (BBD) models reveals significant correlations and interactions between the manipulated and response variables. To establish the optimum pre-treatment conditions, the experiment used the design BBD, using Design Expert (Design Expert 10.0.3) software. This ensures that the process engineers and scientists gain a better understanding of the practical application of the experimental results over the conventional method of one-factor-at-time (OFAT). The recent trend in industrialization and population growth has indeed deepened the demand on the world's energy (oil) and water resources. However, the need to meet the significance of energy and water for sustainable social economy growth and development has resulted in extremely adverse effects on water and environmental pollution. South Africa, well known as a water scarcity country, has also intensified its policy and increased fines for offenders who do not meet its regulations and discharge limits. In this context, the treatment of industrial mineral oil wastewater, which is regarded as hazardous and harmful to the environment, derived from petrochemical and oil refinery industries, has a recovery value. This has raised attention for systematic technology and approach in recovering oil and water for reuse to conserve the supply of fresh water and energy resources.
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