The incorporation of benzodithiazolyl (BDTA) and methylbenzodithiazolyl (MBDTA) radicals into porous hybrid frameworks via gas phase diffusion revealed that inclusion appeared selective for the MIL53(Al) framework against a range of other potential hosts. Both PXRD and EPR studies are consistent with retention of a π*-π* dimer motif for BDTA in MIL53(Al)@BDTA whereas MBDTA in MIL53(Al)@MBDTA appears to be monomeric. The guests are readily released by the addition of solvent (CH(2)Cl(2)).

Wide-scale deployment of variable renewable energy (wind and solar photovoltaic) is constrained by its associated requirements for energy storage, the technologies for which are currently too expensive to be routinely used. Concentrated solar power (CSP), with its inherent storage capacity, offers semi-dispatchable electricity at large scale. However, its deployment to date has been restricted by high capital costs and the limited geographical locations with optimal solar radiation to attain required efficiencies. South Africa, with its abundant solar resources, has the potential to develop an export-competitive CSP industry by leveraging existing capabilities in innovation, manufacturing and construction, but has yet to attain this goal. This study applied a qualitative, exploratory approach and the framework of technological innovation systems (TIS) to understand the factors that are currently prohibiting the country from being a global leader in CSP. The assessment has revealed the presence of largely immature TIS, characterised by a heavy reliance on imported technology and market support from the state-supported procurement programme. The advancement of CSP remains contingent on further allocation of CSP procurement targets in this programme and sufficient support to develop entrepreneurial activity. An integrated industrial policy strategy, which can ensure technology transfer and address the high cost of CSP, is recommended as a means of addressing the barriers to its development as a competitive industry.

In the title compound, C14H10O5, each carboxyl group is coplanar with the attached aromatic ring. The dihedral angle between these planes is 72.56 (5)°. The carboxyl groups are linked by a pair of centrosymmetric O—H...O hydrogen bonds, creating a zigzag chain along the [21] direction.

The title compound, C13H16O2Si, was synthesized as a precursor for ethynylarene derivatives and crystallized from hexane. In the crystal structure, mol­ecules are linked by weak C—H⋯O hydrogen bonds to form chains that pack in layers in a herringbone fashion.