New sulfonic acid functionalized ionic liquids (SAFILs) with bis(trifluoromethylsulfonyl)imide anions were synthesized. These ionic liquids are strong Brønsted acids and can solubilize metal oxides. Water-immiscible SAFILs were used as organic phases in solvent extraction studies.
Ionic liquids are generally recognized as highly stable compounds with high thermal decomposition temperatures and wide electrochemical windows. While the former claim has been the subject of recent scrutiny and...
The less polar phase of liquid–liquid extraction systems has been studied extensively for improving metal separations; however, the role of the more polar phase has been overlooked for far too long. Herein, we investigate the extraction of metals from a variety of polar solvents and demonstrate that, the influence of polar solvents on metal extraction is so significant that extraction of many metals can be largely tuned, and the metal separations can be significantly enhanced by selecting suitable polar solvents. Furthermore, a mechanism on how the polar solvents affect metal extraction is proposed based on comprehensive characterizations. The method of using suitable polar solvents in liquid–liquid extraction paves a new and versatile way to enhance metal separations.
Sulfamic acid (NH3-SO3) is an acidic zwitterion with many applications. N-Alkylated derivatives are introduced, which can be used as a new class of metal extractants R2NH-SO3 and as new super-acidic ionic liquids [R2NH-SO3H][Tf2N]. The synthesis, properties and novel applications of this versatile platform are discussed.
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