High-melting phosphonium tosylates are synthesised and applied for the first time as solvents in catalytic hydroformylation reactions; variation in the substituents attached to phosphorus can lead to markedly different results; the catalyst systems are non-corrosive, easily manipulated and can readily be recovered and reused.
1999aldehydes aldehydes (acyclic compounds) P 0170
-082Clean Catalysis with Ionic Solvents -Phosphonium Tosylates for Hydroformylation.-Phosphonium tosylates are applied for the first time as solvent in catalytic hydroformylation. These systems are non-corrosive, easily manipulated and can be readily recovered and reused. -(KARODIA, N.; GUISE, S.; NEWLANDS, C.; ANDERSEN, J.-A.; Chem. Commun. (Cambridge) (1998) 21, 2341-2342; Dep. Chem.,
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