Broader applications of carbon nanotubes to real-world problems have largely gone unfulfilled because of difficult material synthesis and laborious processing. We report high-performance multifunctional carbon nanotube (CNT) fibers that combine the specific strength, stiffness, and thermal conductivity of carbon fibers with the specific electrical conductivity of metals. These fibers consist of bulk-grown CNTs and are produced by high-throughput wet spinning, the same process used to produce high-performance industrial fibers. These scalable CNT fibers are positioned for high-value applications, such as aerospace electronics and field emission, and can evolve into engineered materials with broad long-term impact, from consumer electronics to long-range power transmission.O n the molecular level, carbon nanotubes (CNTs) have an outstanding combination of mechanical strength and stiffness, electrical and thermal conductivity, and low density, making them ideal multifunctional materials that combine the best properties of polymers, carbon fibers, and metals (1). However, such outstanding properties have remained elusive on a macroscopic scale. Handling CNTs with sufficient length, stiffness, and chemical inertness introduces major challenges in material processing. Here we report lightweight fibers that approach the high specific strength of polymeric and carbon fibers, while also achieving the high specific electrical conductivity of metals and the specific thermal conductivity of graphite fibers.Two distinct routes have been developed for manufacturing neat CNT fibers (2). One route employs a solid-state process wherein CNTs are either directly spun into a fiber from the synthesis reaction zone (3, 4) or from a CNT forest grown on a solid substrate (5). This approach does not lend itself to the typical easy scale-up of chemical processes, as it combines multiple steps into a single one, limiting the options for process and material optimization. Indeed, solidstate fibers have low packing and poor orientation, and include impurities within their structure (6). Despite these shortcomings, solid-state CNT fibers have delivered the best properties so far (3, 4, 7-9). The reason for this relative success is the length of the CNTs that constitute these fibers-1 mm or more (2). Longer CNTs reduce the number of CNT ends in a fiber, yielding greater strength (10) and reducing CNT junctions, which increases electrical and thermal conductivity (11). The alternate fiber production route-wet spinning-was the first method for producing CNT fibers (12). In this process, premade CNTs are dissolved or dispersed in a fluid, extruded out of a spinneret, and coagulated into a solid fiber by extracting the dispersant. Wet spinning is easily scaled to industrial levels and is indeed the route by which highperformance fibers are manufactured (including ballistic fibers such as Kevlar and Twaron and structural fibers such as Toho Tenax and Thornel carbon fibers) (13). Decoupling the synthesis of CNTs from the spinning of the fibers allo...
Hysteresis in the field emission (FE) data of a chemical vapor synthesized carbon nanotube fiber cathode is analyzed in the regime where self-heating effects are negligible. In both the forward and reverse applied field sweeps, various FE modes of operation are identified: including Fowler-Nordheim (FN) tunneling and space-charge limited emission from the fiber tip and FN emission from the fiber sidewall. Hysteresis in the FE data is linked to the difference in the field enhancement factors in the different FE modes of operation in the forward and reverse sweeps and related to changes in the fiber morphology.
Digital image correlation of laser-ablated platinum nanoparticles on the surface of a polycrystalline metal (nickel-based superalloy Rene´88DT) was used to obtain the local strain behavior from an in-situ scanning electron microscope tensile experiment at room temperature. By fusing this information with crystallographic orientations from electron backscatter diffraction (EBSD), a subsequent analysis shows that the average maximum shear strain tends to increase with increasing Schmid factor. Additionally, the range of the extreme values for the maximum shear strain also increases closer to the grain boundary, signifying that grain boundaries and triple junctions accumulate plasticity at strains just beyond yield in polycrystalline Rene´88DT. In-situ experiments illuminating microstructure-property relationships of this ilk may be important for understanding damage nucleation in polycrystalline metals at high temperatures.
In this work, we quantify field emission properties of cathodes made from carbon nanotube (CNT) fibers. The cathodes were arranged in different configurations to determine the effect of cathode geometry on the emission properties. Various geometries were investigated including: 1) flat cut fiber tip, 2) folded fiber, 3) looped fiber and 4) and fibers wound around a cylinder. We employ a custom field emission microscope to quantify I-V characteristics in combination with laterallyresolved field-dependent electron emission area. Additionally we look at the very early emission stages, first when a CNT fiber is turned on for the first time which is then followed by multiple ramp-up/down. Upon the first turn on, all fibers demonstrated limited and discrete emission area. During ramping runs, all CNT fibers underwent multiple (minor and/or major) breakdowns which improved emission properties in that turn-on field decreased, field enhancement factor and emission area both increased. It is proposed that breakdowns are responsible for removing initially undesirable emission sites caused by stray fibers higher than average. This initial breakdown process gives way to a larger emission area that is created when the CNT fiber sub components unfold and align with the electric field. Our results form the basis for careful evaluation of CNT fiber cathodes for dc or low frequency pulsed power systems in which large uniform area emission is required, or for narrow beam high frequency applications in which high brightness is a must.
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