Levels of BTEX (benzene, toluene, ethylbenzene, and p-xylene) were determined in ambient air of an urban site located at the center of Mexico (Leon City in Guanajuato State) during two climatic seasons of 2018 (summer and autumn). Ethylbenzene (11.86 µg m−3) and toluene (11.85 µg m−3) showed the highest median concentrations during the study period. BTEX concentrations did not show a diurnal pattern but a seasonal trend was observed for benzene and toluene at a significant level of α = 0.05. Bi-variate and multivariate analysis showed significant positive correlations (at α = 0.05) among BTEX (excepting benzene), indicating common sources for toluene, ethylbenzene, and p-xylene and a different origin for benzene. A meteorological study was also conducted in order to determine the origin of air masses that could influence the BTEX concentrations in the study site. Finally, it was found that all BTEX species presented hazard quotient values (HQs) <1, indicating that there is no risk of non-cancer during the studied period. Lifetime cancer risk due to benzene exposure for the adult and child populations studied were estimated to be 7 in 1,000,000 and 1 in 100,000, respectively.

Trace metal concentrations in PM10 were measured in an urban–industrial site in León, Mexico in three different seasons. PM10 were collected in quartz fiber filters of 47 mm diameter using low volume equipment operating with a controlled flow of 5 L min−1 over 24 h. Mass concentrations were gravimetrically determined and it was found that PM10 samples showed values in excess of the Mexican standard and the established values by WHO during cold dry and warm dry seasons. Morphology of selected particles was studied by SEM-EDS analysis, and the elemental composition was determined. Collected samples were analyzed by atomic absorption spectrometry in order to quantify ambient air concentrations of some trace metals (Cu, Co, Zn, Cd, Fe, Mg, and Mn). Median concentrations of trace metals showed the maximum value for iron (3.079 μgm−3) and the minimum value for Cd (0.050 μgm−3) over the entire period. From the meteorological analysis, it was found that sources located SW and ESE of the sampling site contributed to the levels of trace metals in PM10 in the studied site. The health risk assessment found that the population of León is at increased lifetime risk of experiencing cancer because of exposure to these concentrations of PM10 and their trace metal content.