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Mesozoic melilite-bearing ultrama®c lamprophyres are developed as sill, dyke and plug-like intrusive bodies in the East Antarctic Beaver Lake area. They consist of varying amounts of olivine, melilite, phlogopite, nepheline, titanomagnetite and perovskite as major phases, accompanied by minor amounts of apatite, carbonate, spinel, glass and, rarely, monticellite. The rocks are mineralogically and geochemically broadly similar to olivine melilitites, differing in higher CO 2 and modal phlogopite and carbonate contents. The ultrama®c lamprophyres are MgO-rich (13.4±20.5 wt%) and SiO 2 -poor (32.8±37.2 wt%), indicative of a near-primary nature. Major and trace element features are consistent with minor fractionation of olivine and Cr-spinel from melts originating at depths of 130±140 km.Primary melts originated by melting of upper mantle peridotite which had been veined by phlogopite carbonate clinopyroxene-bearing assemblages less than 200 Ma before eruption. The presence of the veins and their time of formation is required to explain high incompatible trace element contents and growth of 87 Sr= 86 Sr, leaving 143 Nd= 144 Nd unaffected. The major element, compatible trace element, and most radiogenic isotope characteristics are derived from melting of the wall-rock peridotite. The depth of about 130 km is indicated by the presence of phlogopite rather than amphibole in the veins, by control of the REE pattern by residual garnet, by the high MgO content of the rocks, and by the expected intersection of the rift-¯ank geotherm with the solidus at this depth. The higher CO 2 contents than are characteristic for olivine melilitites favoured the crystallization of melilite at crustal pressures, and suppressed the crystallization of clinopyroxene. The Beaver Lake ultrama®c lamprophyres are a distal effect of the breakup of Gondwanaland, too distal to show a geochemical signature of the Kerguelen plume. Upward and outward movement of the asthenosphere-lithosphere boundary beneath the Lambert-Amery rift led ®rst to the production of phlogopite-and carbonaterich veins, and later to the generation of the ultrama®c lamprophyres themselves.

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Quantification of the CO2 binding capacity of reinforced concrete is of high importance for predicting the carbonation potential and service life of these structures. Such information is still not available for alkali activated materials that have received extensive attention as a sustainable substitute for ordinary Portland cement (OPC)-based concrete. To address this gap, this paper evaluates the CO2 binding capacity of ground powders of alkali activated fly ash (FA) and ground granulated blast furnace slag (GBFS) pastes under accelerated carbonation conditions (1 % v/v CO2, 60% RH, 20°C) for up to 180 days. The CO2 binding capacity, the gel phase changes, and the carbonate phases are investigated with complementary TG-DTG-MS, FT-IR and QXRD techniques.Five mixtures with different FA/GBFS ratio are considered. CEM I and CEM III/B pastes are also studied to provide a baseline for comparisons. The results showed that the alkaliactivated pastes have a lower CO2 binding capacity in comparison to cement-based pastes. Furthermore, alkali-activated pastes have similar CO2 binding capacity regardless of the FA/GBFS ratio. It was observed that the silicate functional groups corresponding to the reaction products in the pastes were progressively changing during the first 7 days, after which only carbonate groups changed. It was also found that the CO2 bound in the alkali-activated pastes occurs to a substantial extent in amorphous form.

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Forty-seven male patients with mild essential hypertension were randomly allocated to three subgroups. After a run-in period of 4 weeks, the first subgroup (n=16) received propranolol (80 mg/day) for 36 weeks followed by a placebo period of 4 weeks. The second subgroup (n=15), after a run-in period of 4 weeks, was given a supplement of encapsulated fish oil (9 g/day) for 36 weeks with a subsequent period of 4 weeks in which fish oil placebo was given. The third subgroup (n=16), after a run-in period of 4 weeks, was given propranolol (80 mg/day) for 12 weeks, propranolol (80 mg/day) plus fish oil capsules (9 g/day equivalent to 1.8 g/day of eicosapentaenoic acid and 1.1 g/day of docosahexaenoic acid) for 12 weeks, propranolol plus fish oil placebo (same doses for 12 weeks) with a subsequent period of 4 weeks when propranolol placebo was administered. The results indicate a blood pressure-lowering effect of fish oil, which was comparable with that of propranolol. The simultaneous intake of fish oil plus propranolol was more effective than propranolol or fish oil alone. Propranolol treatment resulted in a decrease of plasma norepinephrine, plasma renin activity, and thromboxane B 2 formation. After fish oil supplementation, plasma norepinephrine and thromboxane B 2 formation were likewise reduced, whereas plasma renin activity appeared increased. The decrease of serum triglycerides, total and low density lipoprotein cholesterol as well as the rise of high density lipoprotein cholesterol are concomitant beneficial effects, which justify the consideration of fish oil alone or in combination with antihypertensive drugs for the treatment of mild hypertension. {Hypertension 1990;16:682-691)

Mould powders play an important role in the stability of the continuous casting process of steel. The main functions of mould slag (i.e. molten powder) are to provide sufficient lubrication and to control the heat transfer between the developing steel shell and the mould. Sufficient lubrication requires an undisturbed melting of mould powders and uniform infiltration of mould slag. Based on the casting practice in IJmuiden, it is found that these demands become even more important for the applied high casting speeds in thin slab casting at 5 to 6 m/min. At Corus RD&T, mould powders were characterised by X-ray diffraction and subsequent fUlly quantitative Rietveld analysis. Additionally, the melting of mould powders has been studied in-situ using high-temperature X-ray diffraction, to gain crucial knowledge about melting relations. Slag rims obtained from the thin slab caster mould were characterised using extended microscopic techniques in order to describe the mechanisms of rim formation and growth. Finally, slag films obtained after casting were characterised. As a result, not only the melting process of mould powder, but also the mechanism of formation and growth of slag rims is much better understood. This knowledge will be applied to define the demands on the composition and properties of mould powder for even higher casting speeds.