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More than 50000 tons of CO 2 have been injected at Ketzin into the Stuttgart Formation, a saline aquifer, at approximately 620 m depth, as of the summer 2011. We present here results from the 1 st repeat 3D seismic survey that was performed at the site in the autumn 2009, after about 22000 tons of CO 2 had been injected. We show here that rather complex time-lapse signatures of this CO 2 can be clearly observed within a radius of about 300 m from the injection well. The highly irregular amplitude response within this radius is attributed to the heterogeneity of the injection reservoir. Time delays to a reflection below the injection level are also observed. Petrophysical measurements on core samples and geophysical logging of CO 2 saturation levels allow an estimate of the total amount of CO 2 visible in the seismic data to be made. These estimates are somewhat lower than the actual amount of CO 2 injected at the time of the survey and they are dependent upon the choice of a number of parameters. In spite of some uncertainty, the close agreement between the amount injected and the amount observed is encouraging for quantitative monitoring of CO 2 storage site using seismic methods.

A 3D 25-fold seismic survey with a bin size of 12 by [Formula: see text] and about [Formula: see text] of subsurface coverage was acquired in 2005 near a former natural gas storage site west of Berlin, as part of the five-year EU funded [Formula: see text] project. Main objectives of the seismic survey were to verify earlier geologic interpretations of structure based on vintage 2D seismic and borehole data and to map, if possible, the reservoir pathways in which the [Formula: see text] will be injected at [Formula: see text] depth, as well as providing a baseline for future seismic surveys and planning of drilling operations. The uppermost [Formula: see text] are well imaged and show an anticlinal structure with an east-west striking central graben on its top that extendsdown to the target horizon. About [Formula: see text] of throwis seen on the bounding faults. No faults are imaged near the planned drill sites. Remnant gas, cushion and residual gas, is present near the top of the anticline in the depth interval of about [Formula: see text] and has a clear seismic signature; both higher amplitudes in the reservoir horizons and velocity pulldown are observed. Amplitude mapping of these remnant gas horizons shows that they do not extend as far south as the injection site, which is located on the southern flank of the anticline. Amplitude anomalies, gas chimneys along an east-west striking fault, show that the stored or remnant gas either has been or is presently migrating out of the reservoir formations. Summed amplitude mapping of the planned injection horizon indicates that this lithologically heterogeneous formation may be more porous at the injection site.

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The Ketzin pilot site, led by the GFZ German Research Centre for Geosciences, is Europe's longestoperating on-shore CO 2 storage site with the aim of increasing the understanding of geological storage of CO 2 in saline aquifers. Located near Berlin, the Ketzin pilot site is an in situ laboratory for CO 2 storage in an anticlinal structure in the Northeast German Basin.

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