[1] To date, coral-based paleoclimate research in the Pacific has primarily utilized core samples from the genus Porites and has been most successful reconstructing past variability on interannual timescales, particularly the El Niño Southern Oscillation (ENSO). The Indo-Pacific coral genus Diploastrea, however, owing to its slower extension rate, denser structure, and longer lifespan, can potentially preserve geochemical proxy records 2-3 times longer than Porites cores of the same length. Before its potential can be realized, Diploastrea must first be calibrated and its climate signal assessed. We present oxygen isotope (d 18 O) and Sr/Ca results from two Diploastrea cores collected in Fiji (16°49 0 S, 179°14 0 E) that allow for simultaneous evaluation of this coral's paleoclimatic utility and the reproducibility of each tracer at this site. Comparison to a Porites record from the same location allows for further evaluation of Diploastrea as a paleoclimatic archive. We demonstrate that Diploastrea's septal and columellar material yield similar d 18 O-SST relationships and that despite some sacrifice of the seasonal d 18 O amplitude, bulk sampling of either region is satisfactory for resolving interannual and lower frequency modes of climatic variability. Therefore paleoclimate reconstructions employing either a septal or columellar sampling regime of this genus may be useful at filling in spatial and temporal sampling gaps which currently hinder the reconstruction of long-term changes in major climate fields in the western Pacific.
Despite the presence of numerous active volcanoes in the northern half of Ecuador, few, if any, distal tephras have been previously recognized in the southern one third of the country. In this article, we document the presence of thin (0.1-1.0-cm-thick) distal tephras comprising glass and/or phenocrysts of hornblende and feldspar in sediment cores from five glacial lakes and one bog in Las Cajas National Park (2 • 40 -3 • 00 S, 79 • 00 -79 • 25 W). The lake cores contain from 5 to 7 tephras, and each has a diagnostic major element geochemistry as determined from electron microprobe analysis of ∼710 glass shards and ∼440 phenocrysts of feldspar and hornblende. The loss of sodium with exposure to the electron microbeam causes a 10 ± 7 wt.% (±1σ ) reduction in Na content, which we empirically determined and corrected for before correlating tephras among the sediment cores. We use a similarity coefficient to correlate among the sediment cores; pair-wise comparison of all tephras generally yields an unambiguous correlation among the cores. Six tephras can be traced among all or most of the cores, and several tephras are present in only one or two of the cores. Twenty-six accelerator mass spectrometry 14 C dates on macrofossils preserved in the sediment cores provide the basis for establishing a regional tephrochronology. The widespread tephras were deposited ∼9900, 8800, 7300, 5300, 2500, and 2200 cal yr B.P. The oldest tephras were deposited ∼15,500 and 15,100 cal yr B.P., but these are not found in all cores. Two of the tephras appear correlative with volcaniclastic strata on the flanks of Volcán Cotopaxi and one tephra may correlate with strata on the flanks of Volcán Ninahuilca; both volcanoes are in central Ecuador.
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