New criteria for choosing measurement strategies and assessing data quality allow better comparison of XRF results.

Abstract. The last interglacial serves as an excellent time interval for studying climate dynamics during past warm periods. Speleothems have been successfully used for reconstructing the paleoclimate of last interglacial continental Europe. However, all previously investigated speleothems are restricted to southern Europe or the Alps, leaving large parts of northwestern Europe undocumented. To better understand regional climate changes over the past, a larger spatial coverage of European last interglacial continental records is essential, and speleothems, because of their ability to obtain excellent chronologies, can provide a major contribution. Here, we present new, high-resolution data from a stalagmite (Han-9) obtained from the Han-sur-Lesse Cave in Belgium. Han-9 formed between 125.3 and ∼ 97 ka, with interruptions of growth occurring at 117.3-112.9 and 106.6-103.6 ka. The speleothem was investigated for its growth, morphology and stable isotope (δ 13 C and δ 18 O) composition. The speleothem started growing relatively late within the last interglacial, at 125.3 ka, as other European continental archives suggest that Eemian optimum conditions were already present during that time. It appears that the initiation of Han-9 growth is caused by an increase in moisture availability, linked to wetter conditions around 125.3 ka. The δ 13 C and δ 18 O proxies indicate a period of relatively stable conditions after 125.3 ka; however, at 120 ka the speleothem δ 18 O registered the first signs of regionally changing climate conditions, being a modification of ocean source δ 18 O linked to an increase in ice volume towards the Marine Isotope Stage (MIS) 5e-5d transition. At 117.5 ka, drastic vegetation changes are recorded by Han-9 δ 13 C immediately followed by a cessation of speleothem growth at 117.3 ka, suggesting a transition to significantly dryer conditions. The Han-9 record covering the early Weichselian displays larger amplitudes in both isotope proxies and changes in stalagmite morphology, evidencing increased variability compared to the Eemian. Stadials that appear to be analogous to those in Greenland are recognized in Han-9, and the chronology is consistent with other European (speleothem) records. Greenland Stadial 25 is reflected as a cold/dry period within Han-9 stable isotope proxies, and the second interruption in speleothem growth occurs simultaneously with Greenland Stadial 24.

This study presents subdaily resolved chemical records through fossil mollusk shell calcite. Trace element profiles resolve periodic variability across ~40‐μm‐thin daily growth laminae in a Campanian Torreites sanchezi rudist bivalve. These high‐resolution records are combined with seasonally resolved stable isotope and trace element records that allow shell‐chemical variability to be discussed on both seasonal and daily scale. A combination of layer counting, spectral analysis of chemical cyclicity and chemical layer counting shows that the rudist precipitated 372 daily laminae per year, demonstrating that length of day has increased since the Late Cretaceous, as predicted by astronomical models. This new approach to determine the length of a solar day in geologic history through multiproxy chemical records at subdaily resolution yields considerably more control on the uncertainty of this estimate. Daily chemical variability exceeds seasonal variability in our records, and cannot be explained by diurnal temperature changes. Instead, we postulate that rudist shell chemistry is driven on a daily scale by changes in light intensity. These results together with those of stable isotope analyses provide strong evidence that Torreites rudists had photosymbionts. Bivalve shell calcite generally preserves well. Therefore, this study paves the way for daily‐scale reconstructions of paleoenvironment and sunlight intensity on geologic time scales from bivalve shells, potentially allowing researchers to bridge the gap between climate and weather reconstructions. Such reconstructions improve shell chronologies, document environmental change in warm ecosystems, and widen our understanding of the magnitude of short‐term changes during greenhouse climates.

Abstract. The Last Interglacial serves as an excellent time interval for studying climate dynamics during past warm periods. Speleothems have been successfully used for reconstructing the paleoclimate of Last Interglacial continental Europe. However, all previously investigated speleothems are restricted to southern Europe or the Alpine region, leaving large parts of northwestern Europe undocumented. To better understand regional climate changes over the past, a larger spatial coverage of European Last Interglacial speleothems is essential. Here, we present new, high-resolution data from a stalagmite (Han-9) obtained from the Han-sur-Lesse cave in Belgium. The Han-9 formed between 125.3 and ~97 ka, with interruptions of growth occurring at 117.3–112.9 ka and 106.6–103.6 ka. The speleothem was investigated for its growth, morphology and stable isotope (δ13C and δ18O) content. Speleothem formation within the Last Interglacial started relatively late in Belgium, as this is the oldest sample of that time period found so far, dated at 125.3 ka. Other European continental archives suggest that Eemian optimum conditions were already present during that time, therefore it appears that the initiation of the Han-9 growth is caused by an increase in moisture availability, linked to wetter conditions around 125.3 ka. The δ13C and δ18O proxies indicate a period of relatively stable conditions after 125.3 ka, however at 120 ka the speleothem δ18O registered the first signs of regionally changing climate conditions, being a modification of ocean source δ18O linked to an increase in ice volume towards the MIS 5e-5d transition. The end of the Eemian is marked by drastic vegetation changes recorded in the speleothem δ13C at 117.5 ka, immediately followed by a stop in speleothem growth at 117.3 ka, suggesting that climate became significantly dryer. The Han-9 record covering the Early-Weichselian displays larger amplitudes in both the isotope proxies and the stalagmite morphology, evidencing increased variability compared to the Eemian. Greenland Stadials are recognized in the Han-9 and the chronology is consistent with other European (speleothem) records. Greenland Stadial 25 is reflected as a cold/dry period within the stable isotope proxies and the second interruption in speleothem growth occurs simultaneously with Greenland Stadial 24.

Abstract. Fast-growing speleothems allow for the reconstruction of palaeoclimate down to a seasonal scale. Additionally, annual lamination in some of these speleothems yields highly accurate age models for these palaeoclimate records, making these speleothems valuable archives for terrestrial climate. In this study, an annually laminated stalagmite from the Han-sur-Lesse cave (Belgium) is used to study the expression of the seasonal cycle in northwestern Europe during the Little Ice Age. More specifically, two historical 12-year-long growth periods (ca. 1593–1605 CE and 1635–1646 CE) and one modern growth period (1960–2010 CE) are analysed on a sub-annual scale for their stable-isotope ratios (δ13C and δ18O) and trace-element (Mg, Sr, Ba, Zn, Y, Pb, U) contents. Seasonal variability in these proxies is confirmed with frequency analysis. Zn, Y and Pb show distinct annual peaks in all three investigated periods related to annual flushing of the soil during winter. A strong seasonal in-phase relationship between Mg, Sr and Ba in the modern growth period reflects a substantial influence of enhanced prior calcite precipitation (PCP). In particular, PCP occurs during summers when recharge of the epikarst is low. This is also evidenced by earlier observations of increased δ13C values during summer. In the 17th century intervals, there is a distinct antiphase relationship between Mg, Sr and Ba, suggesting that processes other than PCP, i.e. varying degrees of incongruent dissolution of dolomite, eventually related to changes in soil activity and/or land-use change are more dominant. The processes controlling seasonal variations in Mg, Sr and Ba in the speleothem appear to change between the 17th century and 1960–2010 CE. The Zn, Y, Pb, and U concentration profiles; stable-isotope ratios; and morphology of the speleothem laminae all point towards increased seasonal amplitude in cave hydrology. Higher seasonal peaks in soil-derived elements (e.g. Zn and Y) and lower concentrations of host-rock-derived elements (e.g. Mg, Sr, Ba) point towards lower residence times in the epikarst and higher flushing rates during the 17th century. These observations reflect an increase in water excess above the cave and recharge of the epikarst, due to a combination of lower summer temperatures and increased winter precipitation during the 17th century. This study indicates that the transfer function controlling Mg, Sr and Ba seasonal variability varies over time. Which process is dominant – either PCP, soil activity or dolomite dissolution – is clearly climate driven and can itself be used as a palaeoenvironment proxy.