Permian large-scale transcurrent tectonics and massive magmatism are prominent features of the Tianshan belt and neighboring regions of the Central Asian Orogenic Belt. Structural, geochronological and geochemical analyses of Carboniferous and Permian intrusive rocks associated with the Kangguer-Huangshan Shear Zone (eastern Chinese North Tianshan) provide constraints on their tectonic setting and the tectonic evolution of the Tianshan belt as well. Carboniferous granitic rocks were emplaced at 338 ؎ 4 Ma and 347 ؎ 2 Ma, respectively, and show geochemical features typical of the calc-alkaline series. These arc-type granites do not display ductile deformation, probably because they were completely cooled at the time of shearing tectonics, and are only offset by brittle strike-slip faults. In contrast, Permian granitoids display pervasive ductile tectonic features diagnostic of synkinematic emplacement. Four gabbro and diorite samples from the East Huangshan intrusive complex yielded zircon U-Pb ages of 267 to 275 Ma, and a granitic dike is dated at 290 ؎ 1 Ma. The granitic dike is cut by en-echelon right-lateral strike-slip faults, and the mafic intrusive complex displays a sigmoidal shape with mylonitic foliation localized at its margins. Other specific pluton shapes (such as tongue and tadpole-like) and synmagmatic deformation can be observed in intrusions of the same age, showing similar fabrics and kinematics consistent with that of the Kangguer-Huangshan Shear Zone. Numerous mafic to felsic dikes occur within and off the shear zone with a dominant SE-NW orientation and minor varieties in N-S or NNE-SSW directions.One gabbro dike that intrudes the early Carboniferous granite of the East Kanggurtag area yielded a magmatic age of 274 ؎ 4 Ma, and contains older zircons (ϳ340 Ma, ϳ390 Ma, ϳ450 Ma, and 1.3-2.2 Ga) probably inherited from intruded rocks. The Permian intrusive rocks have variable chemical compositions suggesting derivation of these rocks from depleted and undepleted (or enriched) mantle sources with involvement of subductionrelated components. We conclude from our integrated analysis of the geological, structural, geochemical and geochronological data that the Permian magmatic rocks were formed in a post-collisional/post-orogenic setting from multiple sources, and were emplaced under the control of large-scale dextral transcurrent tectonics.

a b s t r a c tWhilst petrology, geochemistry and metal content of small mafic/ultramafic Ni-Cu bearing complexes have been extensively studied, their structural controls and emplacement mechanisms are still poorly documented. This study addresses the last two points with the Huangshan Ni-Cu ore belt (Chinese Eastern Tianshan) as a case study. The Huangshan intrusions are Early Permian; a period when the Tianshan orogenic belt recorded major right-lateral wrench tectonics, characterized by crustal-scale shear zones. Detailed mapping, petro-structural analysis and strain rate calculation within and around the intrusions allow us to establish that the Huangshan Ni-Cu-bearing mafic/ultramafic complexes are not layered intrusions. Instead, they emplaced by injection of several mafic/ultramafic magma batches within kilometre-scale tension gashes generated by Permian dextral shearing, and should be considered as synkinematic sheeted intrusions. Finite strain analysis across the Huangshan-Kangguer shear zone provides rather high shear strain rates (4.5). Considering the location and alignment of the Ni-Cu-bearing mafic/ultramafic bodies along regional shear zones throughout Eastern Tianshan, it appears that wrench tectonics most likely controlled and focussed the intrusion of parent magmas. As a consequence, rifting related to post-orogenic extension is not required to account for Permian magmatic features of the Tianshan Belt. Finally, the Huangshan Ni-Cu bearing mafic/ultramafic intrusions are neither parts of an ophiolitic suture, nor of a dunite-cored Alaskan-type ore deposit, as postulated in some previous studies. In the light of these new results, we believe that structural controls and emplacement mechanisms of many NiCu sulphides deposits hosted by small intrusions (particularly funnel-shaped ones) should be (re-)evaluated from a structural and geophysical point of view.

The aim of this study was to provide information about the biological properties of iron oxide nanoparticles (IO-NPs) obtained in an aqueous suspension. The IO-NPs were characterized by transmission electron microscopy (TEM). Analysis of hysteresis loops data at room temperature for magnetic IO-NPs sample indicated that the IO-NPs were superparamagnetic at room temperature. The calculated saturation magnetization for magnetic iron oxide wasMs= 18.1 emu/g. The antimicrobial activity of the obtained PMC-NPs was tested against Gram-negative (Pseudomonas aeruginosa1397,Escherichia coliATCC 25922), Gram-positive (Enterococcus faecalisATCC 29212,Bacillus subtilisIC 12488) bacterial as well as fungal (Candida krusei963) strains. The obtained results suggested that the antimicrobial activity of IO-NPs is dependent on the metallic ions concentrations and on the microbial growth state, either planktonic or adherent. The obtained IO-NPs exhibited no cytotoxic effect on HeLa cells at the active antimicrobial concentrations.

The Jbel Saghro is interpreted as part of a long-lived silicic large igneous province. The area comprises two lithostructural complexes. The Lower Complex consists of folded metagreywackes and N070–090°E dextral shear zones, which roughly results from a NW–SE to NNW–SSE shortening direction related to a D1 transpressive tectonic stage. D1 is also combined with syntectonic plutons emplaced between ca. 615 and 575 Ma. The Upper Complex is defined by ash-flow caldera emplacements, thick and widespread ignimbrites, lavas and volcaniclastic sedimentary rocks with related intrusives that were emplaced in three main magmatic flare ups at ca. 575, 565 and 555 Ma. It lies unconformably on the Lower Complex units and was affected by a D2 trantensive tectonic stage. Between 550 and 540 Ma, the magmatic activity became slightly alkaline and of lower extent. Ore deposits show specific features, but remain controlled by the same structural setting: a NNW–SSE shortening direction related to both D1 and D2 stages. Porphyry Au(–Cu–Mo) and intrusion-related gold deposits were emplaced in an earlier stage between 580 and 565 Ma. Intermediate sulfidation epithermal deposits may have been emplaced during lull periods after the second and (or) the third flare-ups (560–550 Ma). Low sulfidation epithermal deposits were emplaced late during the felsic alkaline magmatic stage (550–520 Ma). The D2 stage, therefore, provided extensional structures that enabled fluid circulations and magmatic-hydrothermal ore forming processes.

International audienceSix non-sulfide Zn-Pb ore deposits were investigated in the Moroccan High Atlas, to understand processes and timing of their formation. Sulfide and non-sulfide ores are hosted in Lower Jurassic reefal to para-reefal limestone. Zn (Pb) carbonates, Zn silicates and associated hydrated phases directly replace the stratabound primary ore bodies or fill cavities along fractures related to the Atlasic compression. Field observation has been complemented by a multidisciplinary approach (e.g. XRD, Raman, SEM, EPMA) for the mineralogical characterization. All six ore deposits present similar parageneses revealing three successive stages for ore deposition: 1) formation of the protore sulfides, 2) early supergene weathering with formation of Zn-Pb-bearing carbonates and iron oxi-hydroxides and 3) late supergene weathering with deposition of Zn-carbonates, Zn-silicates and hydrated phases. Direct replacement of primary sulfides is accompanied by precipitation of zinc non-sulfide minerals in cavities or internal sediments filling. The proposed three-step scenario can be placed within the tectonic evolution of the Moroccan High Atlas belt. Deposition of primary sulfides is contemporaneous with opening of the Tethyan and Atlantic oceans. During the Tertiary, intracontinental deformation has given rise to the High Atlas fold-and-thrust belt and to regional uplift. As a result, Zn-Pb sulfides, hosted in carbonates experienced oxidation under an arid climate to form karst-related Zn-Pb non-sulfide ore bodies

International audienceIn the Rio Tinto district of the Iberian Pryrite Belt of South Spain, the weathering of massive sulfide bodies form iron caps, i.e., true gossans and their subsequent alteration and re-sedimentation has resulted in iron terraces, i.e., displaced gossans. To study the stucture and evolution of both types of gossans, magnetic investigations have been carried out with two foci: (1) the characterisation and spatial distribution of magnetic fabrics in different mineralised settings, including massive sulfides, gossans, and terraces, and (2) paleomagnetic dating. Hematite has been identified as the suceptibility carrier in all sites and magnetic fabric investigation of four gossans reveals a vertical variation from top to bottom, with: (1) a horizontal foliation refered to as "mature" fabric in the uppermost part of the primary gossans, (2) highly inclined or vertical foliation interpreted as "immature" fabric between the uppermost and lowermost parts, and (3) a vertical foliation interpreted to be inherited from Hercynian deformation in the lowermost part of the profiles. In terraces, a horizontal foliation dominates and is interpreted to be a "sedimentary" fabric. Rock magnetic studies of gossan samples have identified goethite as the magnetic remanence carrier for the low-temperature component, showing either a single direction close to the present Earth field (PEF) direction or random directions. Maghemite, hematite, and occasionally magnetite are the remanence carriers for the stable high-temperature component that is characterized by non PEF directions with both normal and reversed magnetic polarities. No reliable conclusion can be yet be drawn on the timing of terrace magnetization due to the small number of samples. In gossans, the polarity is reversed in the upper part and normal in the lower part. This vertical distribution with a negative reversal test suggests remanence formation during two distinct periods. Remanence in the upper parts of the gossans is older than in the lower parts, indicating that the alteration proceeded from top to bottom of the profiles. In the upper part, the older age and the horizontal "mature" fabric is interpreted to be a high maturation stage of massive sulfides' alteration. In the lower part, the age is younger and the inherited "imature" vertical Hercynian fabric indicates a weak maturation stage. These two distinct periods may reflect changes of paleoclimate, erosion, and/or tectonic motion

Deciphering the behavior of fluid flow at the magmatic-hydrothermal transition is crucial to understand physical processes leading to the formation of intrusion-related ore deposits and hence to predict the localization of mineralized bodies. However, the hydrodynamics (direction and velocity) of the hydrothermal fluid flow related to this transitional stage remains poorly constrained. Here we present a coupled textural and chemical study performed on tourmaline growth bands to constrain fluid flow during the initiation of the hydrothermal system of the W-Sn-(Cu) Panasqueira deposit. This exceptional deposit consists of a dense network of flat wolframite and cassiterite-bearing quartz veins intensely developed above a well-known hidden greisen cupola. The W-Sn mineralization is preceded by a tourmalinization stage occurring as metasomatic halos around veins and as selvages developed along the vein-wall-rocks contacts. Results emphasize the key role of the greisen cupola on fluid focusing and the role of fluid overpressure during the vein opening. Velocity values highlight an efficient transport of metals in veins largely dominated by advective process (10-4 to 10-3 m.s-1), whereas fluid flow in the altered wall-rocks is slow and pervasive (10-6 to 10-5 m.s-1), suggesting that the element transport through the metasedimentary host rock was low and limited to the alteration haloes. LA-ICP-MS analyses of tourmaline growth bands reveal that fluids coming from the cupola are enriched in Na, K, Li, Sr and Sn, thus emphasizing the contribution of magmatic fluids during the vein formation and the metasomatic alteration of the wall-rocks. More generally, this study demonstrates that the apical portions of granite bodies play as emanative centers of mineralized fluids, and highlights the usefulness of mineral growth band analysis in the search for intrusion-related mineralization.

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