Security of supply of a number of raw materials is of concern for the European Union; foremost among these are the rare earth elements (REE), which are used in a range of modern technologies. A number of research projects, including the EURARE and ASTER projects, have been funded in Europe to investigate various steps along the REE supply chain. This paper addresses the initial part of that supply chain, namely the potential geological resources of the REE in Europe. Although the REE are not currently mined in Europe, potential resources are known to be widespread, and many are being explored. The most important European resources are associated with alkaline igneous rocks and carbonatites, although REE deposits are also known from a range of other settings. Within Europe, a number of REE metallogenetic belts can be identified on the basis of age, tectonic setting, lithological association and known REE enrichments. This paper reviews those metallogenetic belts and sets them in their geodynamic context. The most well-known of the REE belts are of Precambrian to Palaeozoic age and occur in Greenland and the Fennoscandian Shield. Of particular importance for their REE potential are the Gardar Province of SW Greenland, the Svecofennian Belt and subsequent Mesoproterozoic rifts in Sweden, and the carbonatites of the Central Iapetus Magmatic Province. However, several zones with significant potential for REE deposits are also identified in central, southern and eastern Europe, including examples in the Bohemian Massif, the Iberian Massif, and the Carpathians.
This paper explores flows and stocks, at the scale of the European Union, of certain rare earth elements (REEs; Pr, Nd, Eu, Tb, Dy and Y) which are associated with products that are important for the decarbonisation of the energy sector and that also have strong recycling potential. Material flow analyses were performed considering the various steps along the value chain (separation of rare earth oxides, manufacture of products, etc.) and including the lithosphere as a potential stock (potential geological resources). Results provide estimates of flows of rare earths into use, in-use stocks and waste streams. Flows into use of, e.g., Tb in fluorescent lamp phosphors, Nd and Dy in permanent magnets and Nd in battery applications were estimated, for selected reference year 2010, as 35, 1230, 230 and 120 tons respectively. The proposed Sankey diagrams illustrate the strong imbalance of flows of permanent magnet REEs along the value chain, with Europe relying largely on the import of finished products (magnets and applications). It is estimated that around 2020, the amounts of Tb in fluorescent lamps and Nd in permanent magnets recycled each year in Europe, could be on the order of 10 tons for Tb and between 170 and 230 tons for Nd.
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The Jbel Saghro is interpreted as part of a long-lived silicic large igneous province. The area comprises two lithostructural complexes. The Lower Complex consists of folded metagreywackes and N070–090°E dextral shear zones, which roughly results from a NW–SE to NNW–SSE shortening direction related to a D1 transpressive tectonic stage. D1 is also combined with syntectonic plutons emplaced between ca. 615 and 575 Ma. The Upper Complex is defined by ash-flow caldera emplacements, thick and widespread ignimbrites, lavas and volcaniclastic sedimentary rocks with related intrusives that were emplaced in three main magmatic flare ups at ca. 575, 565 and 555 Ma. It lies unconformably on the Lower Complex units and was affected by a D2 trantensive tectonic stage. Between 550 and 540 Ma, the magmatic activity became slightly alkaline and of lower extent. Ore deposits show specific features, but remain controlled by the same structural setting: a NNW–SSE shortening direction related to both D1 and D2 stages. Porphyry Au(–Cu–Mo) and intrusion-related gold deposits were emplaced in an earlier stage between 580 and 565 Ma. Intermediate sulfidation epithermal deposits may have been emplaced during lull periods after the second and (or) the third flare-ups (560–550 Ma). Low sulfidation epithermal deposits were emplaced late during the felsic alkaline magmatic stage (550–520 Ma). The D2 stage, therefore, provided extensional structures that enabled fluid circulations and magmatic-hydrothermal ore forming processes.
This is a PDF file of an unedited manuscript that has been accepted for publication. As a service to our customers we are providing this early version of the manuscript. The manuscript will undergo copyediting, typesetting, and review of the resulting proof before it is published in its final form. Please note that during the production process errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal pertain. Structural control, magmatic-hydrothermal evolution and formation of hornfels-hosted, intrusion-related gold deposits: Insight from the Thaghassa deposit in Eastern Anti-Atlas, Morocco.
The results of this study allow the reassessment of the rare earth elements (REE) external cycle. Indeed, the river input to the oceans has relatively flat REE patterns without cerium (Ce) anomalies, whereas oceanic REE patterns exhibit strong negative Ce anomalies and heavy REE enrichment. Indeed, the processes at the origin of seawater REE patterns are commonly thought to occur within the ocean masses themselves. However, the results from the present study illustrate that seawater-like REE patterns already occur in the truly dissolved pool of river input. This leads us to favor a partial or complete removal of the colloidal REE pool during estuarine mixing by coagulation, as previously shown for dissolved humic acids and iron. In this latter case, REE fractionation occurs because colloidal and truly dissolved pools have different REE patterns. Thus, the REE patterns of seawater could be the combination of both intra-oceanic and riverine processes. In this study, we show that the Atlantic continental shelves could be considered potential REE traps, suggesting further that shelf sediments could potentially become a resource for REE, similar to metalliferous deep sea sediments.
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