In this paper, we study the behavior of a fluid‐saturated fault under shear, based on the assumption that the material inside exhibits rate‐ and temperature‐dependent frictional behavior. A creeping fault of this type can produce excess heat due to shear heating, reaching temperatures which are high enough to trigger endothermic chemical reactions. We focus on fluid‐release reactions and incorporate excess pore pressure generation and porosity variations due to the chemical effects (a process called chemical pressurization). We provide the mathematical formulation for coupled thermo‐hydro‐chemo‐mechanical processes and study the influence of the frictional, hydraulic, and chemical properties of the material, along with the boundary conditions of the problem on the behavior of the fault. Regimes of stable‐frictional sliding and pressurization emerge, and the conditions for the appearance of periodic creep‐to‐pressurization instabilities are then derived. The model thus extends the classical mechanical stick‐slip instabilities by identifying chemical pressurization as the process governing the slip phase. The different stability regimes identified match the geological observations about subduction zones. The model presented was specifically tested in the Episodic Tremor and Slip sequence of the Cascadia megathrust, reproducing the displacement data available from the GPS network installed. Through this process, we identify that the slow slip events in Cascadia could be due to the in situ dehydration of serpentinite minerals. During this process, the fluid pressures increase to sublithostatic values and lead to the weakening of the creeping slab.
This work studies the transient behavior of a chemically active, fluid‐saturated fault zone under shear. These fault zones are displaying a plethora of responses spanning from ultrafast instabilities, like thermal pressurization, to extremely slow creep localization events on geological timescales. These instabilities can be described by a single model of a rate‐dependent and thermally dependent fault, prone to fluid release reactions at critical temperatures which was introduced in our companion work. In this study we integrate it in time to provide regimes of stable creep, nonperiodic and periodic seismic slip events due to chemical pressurization, depending on the physical properties of the fault material. It is shown that this chemically induced seismic slip takes place in an extremely localized band, several orders of magnitude narrower than the initial shear zone, which is indeed the signature field observation. Furthermore, in the field and in laboratory experiments the ultralocalized deformation is embedded in a chemical process zone that forms part of the shear zone. The width of this zone is shown here to depend on the net activation energy of the chemical reaction. The larger the difference in forward and backward activation energies, the narrower is the chemical process zone. We apply the novel findings to invert the physical parameters from a 16year GPS observation of the Cascadia episodic tremor and slip events and show that this sequence is the fundamental mode of a serpentinite oscillator defined by slow strain localization accompanying shear heating and chemical dehydration reaction at the critical point, followed by diffusion and backward reaction leading the system back to slow slip.
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