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Centrifugal casting of composites and ceramics has been widely employed to improve the mechanical and thermal properties of functional materials. This powerful method has yet to be deployed in the context of nanoparticles—yet size–effect tuning of quantum dots is among their most distinctive and application-relevant features. Here we report the first gradient nanoparticle films to be constructed in a single step. By creating a stable colloid of nanoparticles that are capped with electronic-conduction-compatible ligands we were able to leverage centrifugal casting for thin-films devices. This new method, termed centrifugal colloidal casting, is demonstrated to form films in a bandgap-ordered manner with efficient carrier funnelling towards the lowest energy layer. We constructed the first quantum-gradient photodiode to be formed in a single deposition step and, as a result of the gradient-enhanced electric field, experimentally measured the highest normalized detectivity of any colloidal quantum dot photodetector.

Porous bioceramics, such as hydroxyapatite (HA), tricalcium phosphate (TCP), and biphasic HA/TCP, were fabricated using the polyurethane sponge technique. The porosity of the ceramics was controlled by a multiple coating of the porous body. When a porous body was produced by a single coating, the porosity was ∼90%, and the pores were completely interconnected. When the sintered body was coated five times after the porous network had been made, the porosity decreased to 65%. As the porosity decreased, the strength increased exponentially. The TCP exhibited the highest dissolution rate in a Ringer's solution, and the HA had the lowest rate. The biphasic HA/TCP showed an intermediate dissolution rate.

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A theoretical analysis explaining the whole process of the growth of nanorods on a substrate without a catalyst is presented. Prior to the growth of the nanorods, the reaction precursors form nuclei on the substrate. The nuclei undergo cluster migration caused by the surface diffusion of adatoms on the substrate, and this migration continues until the mean free time of the adatoms is larger than surface diffusion time. The most probable mechanism by which cluster migration takes place is the one that leads to the minimization of the cluster free-energy, namely the migration of six adatoms into one fixed adatom. This cluster migration continues during several (typically smaller than 6) consecutive nuclei growth steps. After the process of cluster migration comes to an end, the nuclei grow in an isotropic manner by collection of the adatoms, until the nucleus reaches the thermodynamic size limit. The one-dimensional growth of nanorods on the nuclei, which is associated with the critical radius, begins when the reactant dose is smaller than a certain value, which is determined by the thermodynamic size limit and the mass transport parameter. The mass transport of the reaction precursors leads to the expansion of the radius and elongation of the height of the nanorods, and the growth rate of the height is greater than that of the radius. This difference in the growth rate causes the aspect ratio to increase with increasing growth time. By comparing the experimental data in the literature (ZnO nanorods), the presented analysis explains well the noncatalytic growth of nanorods on a substrate.

We report on a theoretical analysis of the graphitization of a nanosize diamond (nanodiamond) in the metastable state. A nanodiamond annealed at a relatively lower temperature suffers morphological transition into a nanodiamond–graphite core–shell structure. Thermodynamic stability analysis of the nanodiamond showed that the phase diagram (relationship between the annealing temperature and radius) of the nanodiamond–graphite has three regimes: smaller nanodiamond, nanodiamond–graphite, and larger nanodiamond. These regimes of nanodiamond–graphite are due to an additional phase boundary from finding the maximum size of the nanodiamond which can be graphitized. In the theoretical analysis, the most probable and the maximum volume fractions of graphite in the nanodiamond were 0.76 and 0.84 respectively, which were independent of the annealing temperature and the initial radius of the nanodiamond. Therefore, the nanodiamond is not completely transformed into graphite by simple annealing at relatively lower process temperature and pressure. The highest graphitization probability decreased with increasing annealing temperature. Raman spectra for the F2g vibration mode of nanodiamond were also calculated, and we found that the variation in properties of the spectral line was strongly dependent on the graphitization temperature and the initial size of the nanodiamond.

The coordinate transformation method of asymmetric dual three phase synchronous motor (ADTP-SM) is a Double dq transform using two dq-axes and a vector space decomposition (VSD) model method using the orthogonality of ADTP-SM. There are several studies comparing the two methods in a healthy state, but few in a single-phase open fault state. In the healthy, when the VSD model is applied, different harmonic orders of the phase current are projected onto the dq and xy-axes (the axis for controlling harmonics of the phase current), and the two-axes are orthogonal, so it can be controlled stably. In the single-phase open fault state, the same current control logic as in the healthy situation is applied. When applying the Double dq transform, the dq-axis of the fault set fluctuates, and it affects the healthy set, so it cannot be controlled stably. When applying the VSD model, if both the dq-axis and the xy-axis are controlled, the two coordinate systems do not have orthogonality and cannot be stably controlled, due to mutual interference. However, if only the dq-axis is controlled, it can be controlled stably because there is no Cartesian coordinate system other than the dq-axis. In the healthy state and single-phase open fault state, the equation is verified through experiments and simulations, and the control stability according to the coordinate transformation is compared.