The first use of electrospun nanofibrous membranes as highly responsive fluorescence quenching-based optical sensors for metal ions (Fe3+
and Hg2+) and 2,4-dinitrotoluene (DNT) is reported. A fluorescent polymer, poly(acrylic acid)−poly(pyrene methanol) (PAA−PM), was used as
a sensing material. Optical chemical sensors were fabricated by electrospinning PAA−PM and thermally cross-linkable polyurethane latex
mixture solutions. These sensors showed high sensitivities due to the high surface area-to-volume ratio of the nanofibrous membrane structures.
Blue host materials for organic light-emitting diodes (OLEDs) based on silicon-cored (tetraphenylsilane) anthracene derivatives are synthesized. These compounds, with a non-coplanar molecular structure, have high glass-transition temperatures and good amorphous-film-forming capabilities. When doped with a blue-fluorescent dopant, blue emission with high color purity and high efficiency, up to 7.5 cd A(-1) and 6.3%, is achieved.
We report exceptional electrochemical specific capacitance (640 F g(-1)) for polythiophene (PTh) infiltrated into TiO(2) nanotubes (TNTs) by a controlled electropolymerization route. The resulting PTh-TNTs also exhibit excellent electrochemical behavior with long-term stability. This reproducible and superior performance of PTh-TNT electrodes makes them attractive candidates for energy storage.
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