The recharge ability of zinc metal‐based aqueous batteries is greatly limited by the zinc anode. The poor cycling durability of Zn anodes is attributed to the dendrite growth, shape change and passivation, but this issue has been ignored by using an excessive amount of Zn in the past. Herein, a 3D nanoporous (3D NP) Zn–Cu alloy is fabricated by a sample electrochemical‐assisted annealing thermal method combined, which can be used directly as self‐supported electrodes applied for renewable zinc‐ion devices. The 3D NP architectures electrode offers high electron and ion transport paths and increased material loading per unit substrate area, which can uniformly deposit/strip Zn and improve charge storage ability. Benefiting from the intrinsic materials and architectures features, the 3D NP Zn–Cu alloy anode exhibits high areal capacity and excellent cycling stability. Further, the fabricated high‐voltage double electrolyte aqueous Zn–Br2 battery can deliver maximum areal specific capacity of ≈1.56 mAh cm−2, which is close to the level of typical commercial Li‐ion batteries. The excellent performance makes it an ideal candidate for next‐generation aqueous zinc‐ion batteries.
To meet the increasing requirement of flexible energy storage devices, it is critical to develop an electrode with commercial-level mass loading of active material for supercapacitors. Herein, we fabricated a...
Neutral Zn-air batteries (ZABs) have attracted much attention due to the enhanced lifespan and stability. However, their development is suppressed by the poor catalytic properties of the air-electrocatalysts for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER). Hence, the exploration of highly efficient electrocatalysts for neutral ZABs is critical. Herein, we designed an economical heterostructure of Pt nanoparticle-modified Zn nanoplates (Pt/Zn NPs). Compared with commercial Pt/C electrocatalyst, our Pt/ Zn heterostructure exhibits comparable catalytic properties and ultrahigh stability in neutral media. The heterostructure can reduce the dosage of Pt and offer sufficient active sites, resulting in enhanced catalytic properties for ORR/OER in neutral media. When applied to neutral ZABs as air cathode, our heterostructure exhibits a high power density of 45 mW cm −2 and excellent stability of more than 850 cycles with negligible decay, making it the most efficient and robust one in neutral electrolyte. This approach opens a new avenue to strategically design catalysts with high activity for neutral ZABs, rendering them potential in portable and wearable electronic devices.
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