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Film-like conjugated microporous polymers (CMPs) are fabricated by the novel strategy of carbazole-based electropolymerization. The CMP film storing a mass of counterions acting as an anode interlayer provides a significant power-conversion efficiency of 7.56% in polymer solar cells and 20.7 cd A(-1) in polymer light-emitting diodes, demonstrating its universality and potential as an electrode interlayer in organic electronics.

International audienceThis paper reviews recent progress in the development of the Beijing Climate Center Climate System Model (BCC_CSM) and its four component models (atmosphere, land surface, ocean, and sea ice). Two recent versions are described: BCC_CSM1.1 with coarse resolution (approximately 2.8125°×2.8125°) and BCC_CSM1.1(m) with moderate resolution (approximately 1.125°×1.125°). Both versions are fully coupled climate-carbon cycle models that simulate the global terrestrial and oceanic carbon cycles and include dynamic vegetation. Both models well simulate the concentration and temporal evolution of atmospheric CO2 during the 20th century with anthropogenic CO2 emissions prescribed. Simulations using these two versions of the BCC_CSM model have been contributed to the Coupled Model Intercomparison Project phase five (CMIP5) in support of the Intergovernmental Panel on Climate Change (IPCC) Fifth Assessment Report (AR5). These simulations are available for use by both national and international communities for investigating global climate change and for future climate projections.Simulations of the 20th century climate using BCC_CSM1.1 and BCC_CSM1.1(m) are presented and validated, with particular focus on the spatial pattern and seasonal evolution of precipitation and surface air temperature on global and continental scales. Simulations of climate during the last millennium and projections of climate change during the next century are also presented and discussed. Both BCC_CSM1.1 and BCC_CSM1.1(m) perform well when compared with other CMIP5 models. Preliminary analyses indicate that the higher resolution in BCC_CSM1.1(m) improves the simulation of mean climate relative to BCC_CSM1.1, particularly on regional scales

polymerization (EP) between electroactive moieties such as carbazoles, [ 5 ] which can simultaneously accomplish the controlled polymerization and directed fi lm-forming process in one step. Moreover, this approach offers a powerful tool to precisely control the fi lm thickness by modulating the polymerization conditions, to conveniently manipulate diverse pore structures by designing proper monomers, and to widely tune the electronic conductivities by regulating the doping levels, [ 6 ] thus providing a new platform for functional exploration.Herein we report on the high-performance fi lm-state supercapacitors based on CMP fi lms. We intentionally synthesized a Zn (II) 5,10,15,20-tetrakis[(carbazol-9-yl)phenyl]porphyrin (ZnmTCPP) monomer based on a zinc-porphyrin core and four carbazole peripherals ( Figure 1 ). Zinc porphyrins participate in biological electronic exchange and energy conversion and play an important role in redox processes. They have been widely studied in biomimetics such as oxygen-carrying hemoglobin and electron transfer of cytochrome-c. [ 7 ] N -Substituted carbazole units upon electrooxidative reaction form cation radical species that are highly active in coupling with each other and yield dimer in near-unity effi ciency without the generation of other oligomers. [ 6d,e , 8 ] Both zinc porphyrins and polycarbazoles have been reported to exhibit reversible electrochemical properties which are essential for supercapacitor utilization. [ 9 ] The 3D network structure resulted from the tetrahedral confi guration of the Zn-mTCPP monomer would provide high surface areas and facilitate ion transportation. Through fast and reversible electrochemical reactions, i.e., doping and dedoping, CMP fi lms based on Zn-mTCPP would operate as a promising electrode material of pseudocapacitor to store and release energy.The CMP fi lms were fabricated by cyclic voltammetry (CV) between the potential range of 0-1.4 V in CH 2 Cl 2 with the ZnmTCPP concentration of 1.5 × 10 −5 M ( Figure 2 a,b). During the fi rst cycle of anodic sweep, a broad peak appears from 0.6 to 0.85 V, which is attributed to the oxidation of zinc-porphyrin cores. [ 9c,d ] Another peak at 1.14 V is assigned to the formation of carbazole radical cations, which couple with each other to form dimeric carbazole cations. During the cathodic sweep process, the dimeric carbazole dication is reduced to its neutral state through two one-electron steps, [ 10 ] which results in two peaks at 1.07 and 0.82 V, respectively, whereas the peak appeared at 0.61 V during the backward sweep corresponds to the reduction of oxidized zinc porphyrin. During the second anodic sweep, a new oxidative peak appears at 0.86 V, which is assigned to the oxidation of newly formed dicarbazole groups. A distinct feature is that the current increases with the cycle numbers, which demonstrates that the CMP fi lms gradually grow on Supercapacitors are energy-storage and power-supply devices that are developed to meet the increasing demand for applications in powering vehicle...

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A poly(thieno[3,4‐b]‐thiophene/benzodi­thiophene) (PTB7)‐based polymer solar cell (PSC) with conventional structure can achieve a significant power conversion efficiency of 8.42%, which is realized by integrated optimization of both anode and cathode interlayers. The effects of a conjugated microporous polymer film as the anode interlayer are threefold: it enhances the contact with active layer, increases the work function and conductivity, and blocks electrons.

SummaryHere we describe a proteomic data resource for the NCI-60 cell lines generated by pressure cycling technology and SWATH mass spectrometry. We developed the DIA-expert software to curate and visualize the SWATH data, leading to reproducible detection of over 3,100 SwissProt proteotypic proteins and systematic quantification of pathway activities. Stoichiometric relationships of interacting proteins for DNA replication, repair, the chromatin remodeling NuRD complex, β-catenin, RNA metabolism, and prefoldins are more evident than that at the mRNA level. The data are available in CellMiner (discover.nci.nih.gov/cellminercdb and discover.nci.nih.gov/cellminer), allowing casual users to test hypotheses and perform integrative, cross-database analyses of multi-omic drug response correlations for over 20,000 drugs. We demonstrate the value of proteome data in predicting drug response for over 240 clinically relevant chemotherapeutic and targeted therapies. In summary, we present a novel proteome resource for the NCI-60, together with relevant software tools, and demonstrate the benefit of proteome analyses.

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