Considering nutrient delivery and micronutrient use efficiency problems, mesoporous nanosilica (mNs) and reduced graphene oxide (rGO)-based iron and zinc nanocomposites were formulated. Prepared nanocomposites were characterized for FTIR spectroscopy, XRD, FE-SEM, HR-TEM, and AAS to examine surface functional groups, morphology, and structural composition. XRD spectrum confirmation with SAED image of nanosilica and graphene oxide nanocomposites confirms the polycrystalline and crystalline nature with 30–70-nm crystal size. The SEM revealed that the modified surface of mesoporous nanosilica and reduced graphene oxide are well-distributed clusters and are composed of targeted micronutrients. The impact of nano Fe and Zn foliar application was evaluated on rice grain fortification, productivity, and micronutrient use efficiency. The iron and zinc uptake at 60 days after sowing (DAT) and at harvest was significantly increased with foliar application of mNs and rGO-based Zn at 30 ppm + Fe at 5 ppm nanocomposites as well as led to nutrient fortification by increasing grain uptake and content, with the application of 30 ppm zinc and 5 ppm iron through mNs resulted in an improvement of the rice grain yield by 53% over conventional fertilization. Besides significant increment in grain yield, foliar application of mNs and rGO-based nanocomposites (Zn at 30 ppm + Fe at 5 ppm) increased the Zn and Fe use efficiency by 527 and 380%, respectively, over conventional micronutrient fertilization (ZnSO4 and FeSO4).
In the current study, efforts were made to standardize fertigation for providing the recommended doses of fertilizers (RDF) i.e., 300, 260, and 200 g/plant/year for N, P, and K, respectively, together with optimization of irrigation scheduling so that guava plants could avoid the frequent episodes of nutritional stress, water scarcity, or overwatering. The experiment’s execution was confined to a three-factor randomized block design, with a total of 19 treatments that were replicated four times. Briefly, these treatments included drip irrigation and nutrient (NPK) application through fertigation dosages (RDF; 100, 80, and 60%) with and without silver-black plastic mulching. Different applied fertilizer dosages, together with different levels of irrigation and soil mulching, had a significant impact on the guava plant’s vegetative, reproductive, and nutritional aspects. Under silver-black plastic mulch, drip irrigation at cumulative pan evaporation (CPE) 80 and 100% of the prescribed dosage of fertilizers, better macronutrient availability in the soil, and improved plant development were recorded (M1DI2F1). Overall, using drip fertigation to provide NPK fertilizers close to the root zone increased the availability of nutrients to the plants as compared to the traditional fertigation and irrigation methods. Thus, this sustainable high-tech horticultural approach could be analyzed for its efficacy or applied to other crops to obtain adequate economic outcomes.
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