We show how the growth mode of a thin metallic film on an insulating substrate can be predicted theoretically by combining thermodynamic considerations with ab initio calculations for ordered metal/insulator interfaces at low coverage. Our approach is illustrated by calculations for Ag film deposited on an MgO substrate. Ab initio calculations predict high mobility of adsorbed Ag atoms on MgO, even at low temperatures, which greatly aids their aggregation.

We present experimental results of plasma formation on the surface of ferroelectric samples. Different poled and unpoled ferroelectric samples having a disk or tube form and made of Pb(Zr, Ti)O3 or BaTiO3 were tested. Using fast framing photography and different electric probes it was found that the application of a high-voltage driving pulse to the ferroelectric sample causes a fast surface plasma formation. This plasma formation occurs within a few nanoseconds from the start of the driving pulse for all the tested ferroelectric samples and the methods of applying the driving pulse. It was found that reversing the polarization of a ferroelectric does not play a significant role in the process of the plasma formation. Parameters of the plasma and of the neutral flow formed during the plasma formation versus the polarity and the amplitude of the driving pulse are presented.

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The (001) surface relaxation of the cubic perovskite crystal has been studied using the shell model. The positions of atoms in several surface layers embedded in the electrostatic field of the remainder of the crystal are calculated. We show that , and ions in six near-surface layers are displaced differently from their crystalline sites which leads to the creation of so-called surface rumpling, a dipole moment, and an electric field in the near-surface region. Calculated atomic displacements are compared with LEED experimental data.

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