Long TiO2 hollow fibers with mesoporous walls have been fabricated with the sol-gel combined two-capillary spinneret electrospinning technique using a triblock copolymer (Pluronic, P123, (H(C2H5O)20(C3H7O)70 (C2H5O)20OH) as a pore-directing agent. The as-prepared hollow fibers were as long as 30 cm with an outer diameter of 0.1-4 microm and wall thickness of 60-500 nm. The diameters and wall thicknesses of the hollow fibers could be tuned by adjusting the electrospinning parameters. The fiber walls were composed of mesopores 6.7 nm in diameter as calculated from the N2 adsorption/desorption isotherm. The high-resolution TEM (HR-TEM) images exhibited that the mesopores were hexagonally aligned with a low order because of the curving of the pores. When comparing with other nanostructured TiO2 materials such as commercial TiO2 nanoparticles (P25, Degussa) and mesoporous TiO2 powders, the hollow fibers exhibited higher photocatalytic activities toward degradation of methylene blue and gaseous formaldehyde.
Herein, an example of Cu-doped few-layer ZnIn 2 S 4 nanosheets is used to reveal the origin of optimum and excess doping for photocatalysts at atomic level. Results show that the metal-S 4 coordination maintains well with 0.5 wt% Cu substituted Zn atoms in the lattice. The introduced Cu atoms bring electronic acceptor states close to the valence band (VB) maximum and thus ensures higher charge density and efficient carrier transport, resulting in an optimum hydrogen evolution rate of 26.2 mmol h −1 g −1 and an apparent quantum efficiency of 4.76% at 420 nm. However, a distorted atomic structure and largely upshift of VB maximum with Cu-S 3.6 coordination are found with excess doping concentration (3.6 wt%). These bring the heavy charge recombination and consequentially dramatic reduced activity. This work provides a new insight into elemental doping study and takes an important step toward the development of ultrathin 2D photocatalysts.
Recently, 3D graphene‐based macrostructures (3D GBMs) have gained increased attention due to their immense application potential in water treatment. The unique structural features (e.g., large surface area and physically interconnected porous network) as well as fascinating properties (e.g., high electrical conductivity, excellent chemical/thermal stability, ultralightness, and high solar‐to‐thermal conversion efficiency) render 3D GBMs as promising materials for water purification through adsorption, capacitive deionization, and solar distillation. Moreover, 3D GBMs can serve as scaffolds to immobilize powder nanomaterials to build monolithic adsorbents and photo‐/electrocatalysts, which significantly broadens their potential applications in water treatment. Here, recent advances in their synthesis and application toward water purification are highlighted. Remaining challenges and future perspectives are elaborated to highlight future research directions.
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