A series of ternary sulfide hollow structures have been successfully prepared by a facile glutathione (GSH)-assisted one-step hydrothermal route, where GSH acts as the source of sulfur and bubble template. We demonstrate the feasibility and versatility of this in situ gas-bubble template strategy by the fabrication of novel hollow structures of MInS (M = Cd, Zn, Ca, Mg, and Mn). Interestingly, with the reaction time varying, the hierarchical CdInS microspheres with controlled internal structures can be regulated from yolk-shell, smaller yolk-shell (yolk-shell with shrunk yolk), hollow, to solid. Under visible-light irradiation, all of our prepared CdInS samples with different morphologies were photoactivated. In virtue of the appealing hierarchical hollow structure, the yolk-shell-structured CdInS microspheres exhibited the optimal photocatalytic activity and excellent durability for both the XB degradation and H evolution, which can be ascribed to the synergy-promoting effect of the small crystallite size together with the unique structural advantages of the yolk-shell structure. Thus, we hypothesize that this proof-of-concept strategy paves an example of rational design of hollow structured ternary or multinary sulfides with superior photochemical performance, holding great potential for future multifunctional applications.
Metal selenides have attracted increased attention as promising electrode materials for electrochemical energy storage and conversion systems including metal-ion batteries and water splitting. However, their practical application is greatly hindered by collapse of the microstructure, thus leading to performance fading. Tuning the structure at nanoscale of these materials is an effective strategy to address the issue. Herein, we craft MoSe with hierarchical hollow structures via a facile bubble-assisted solvothermal method. The temperature-related variations of the hollow interiors are studied, which can be presented as solid, yolk-shell, and hollow spheres, respectively. Under the simultaneous action of the distinctive hollow structures and interconnections among the nanosheets, more intimate contacts between MoSe and electrolyte can be achieved, thereby leading to superior electrochemical properties. Consequently, the MoSe hollow nanospheres prepared under optimum conditions exhibit optimal electrochemical activities, which hold an initial specific capacity of 1287 mA h g and maintain great capacity even after 100 cycles as anode for Li-ion battery. Moreover, the Tafel slope of 58.9 mV dec for hydrogen evolution reaction is also attained.
Bismuth oxide silicate (Bi2O2SiO3) single-crystalline nanosheets with exposed {001} facets were synthesized for the first time via a facile one-step CTAB-assisted hydrothermal method in the presence of NaOH.
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