Currently, concentrated electrolyte solutions are attracting special attention because of their unique characteristics such as unusually improved oxidative stability on both the cathode and anode sides, the absence of free solvent, the presence of more anion content, and the improved availability of Li + ions. Most of the concentrated electrolytes reported are lithium bis(fluorosulfonyl)imide (LiFSI) salt with ether-based solvents because of the high solubility of salts in ether-based solvents. However, their poor anti-oxidation capability hindered their application especially with high potential cathode materials (>4.0 V). In addition, the salt is very costly, so it is not feasible from the cost analysis point of view. Therefore, here we report a locally concentrated electrolyte, 2 M LiPF 6 , in ethylene carbonate/diethyl carbonate (1:1 v/v ratio) diluted with fluoroethylene carbonate (FEC), which is stable within a wide potential range (2.5−4.5 V). It shows significant improvement in cycling stability of lithium with an average Coulombic efficiency (ACE) of ∼98% and small voltage hysteresis (∼30 mV) with a current density of 0.2 mA/cm 2 for over 1066 h in Li||Cu cells. Furthermore, we ascertained the compatibility of the electrolyte for anode-free Li−metal batteries (AFLMBs) using Cu||LiNi 1/3 Mn 1/3 Co 1/3 O 2 (NMC, ∼2 mA h/ cm 2 ) with a current density of 0.2 mA/cm 2 . It shows stable cyclic performance with ACE of 97.8 and 40% retention capacity at the 50th cycle, which is the best result reported for carbonate-based solvents with AFLMBs. However, the commercial carbonate-based electrolyte has <90% ACE and even cannot proceed more than 15 cycles with retention capacity >40%. The enhanced cycle life and well retained in capacity of the locally concentrated electrolyte is mainly because of the synergetic effect of FEC as the diluent to increase the ionic conductivity and form stable anion-derived solid electrolyte interphase. The locally concentrated electrolyte also shows high robustness to the effect of upper limit cutoff voltage.
Recently,
metallic zinc (Zn) is becoming a promising ideal anode
material for rechargeable aqueous batteries by providing high theoretical
capacity (820 mA h/g) with divalent reaction, environmental friendliness,
earthy abundance, low cost, low toxicity, higher water compatibility,
and low electrochemical potential (−0.762 V vs SHE). However,
intensive growth of zinc dendrites while plating/stripping lowers
its coulombic efficiency and shortens the cycle life of the rechargeable
devices. Here, we report a concentrated aqueous electrolyte (4.2 M
ZnSO4 + 0.1 M MnSO4) with improved cycling stability
of zinc metal anode achieving an average coulombic efficiency (ACE)
∼99.21% cycling for more than 1000 h at 0.2 mA/cm2 current density using a Zn||Cu cell. However, a frequently used
diluted electrolyte (2 M ZnSO4 + 0.1 M MnSO4) only produces ACE ≈ 97.54% with a relatively short life
cycle. The developed concentrated electrolyte with strongly aggregated
ion pairs shows the synergetic effects of the enhanced solvation/desolvation
process, electrostatic shielding, and Le Chatelier’s principle.
Consequently, the additives simultaneously suppress Zn dendrites and
dissolution of Mn2+ ions from the MnO2 cathode.
A highly stable and reversible Zn||MnO2 cell retaining
about 88.37% retention capacity was obtained after cycling for more
than 1200 cycles at 938 mA/g current density.
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