High-entropy alloys (HEAs), which are defined as near-equimolar alloys of five or more elements, are attracting ever increasing attention because of the unique properties in a variety of applications. Recently, HEAs have already exhibited remarkable catalytic performance toward several thermal-driven and electrocatalytic reactions. HEAs not only regulate the electronic and geometric structures to a large degree but also serve as a platform to construct catalysts with unexpected performance. Herein, recent advances regarding HEA-based catalysis are systematically summarized, with a special focus on the synthetic methods for HEA-based catalysts, catalytic performance, and mechanistic understanding. Moreover, the challenges and future opportunities for this research area are carefully discussed. A series of open questions and promising directions to be explored are proposed, including synthetic methods, regulation of electronic properties, identification of active centers, and applications into photocatalysis. This Review provides an overview about the progress, challenges, and opportunities for HEA-based catalysis.
Abstract-Smart grid is a promising power delivery infrastructure integrated with communication and information technologies. Its bi-directional communication and electricity flow enable both utilities and customers to monitor, predict, and manage energy usage. It also advances energy and environmental sustainability through the integration of vast distributed energy resources. Deploying such a green electric system has enormous and far-reaching economic and social benefits. Nevertheless, increased interconnection and integration also introduce cybervulnerabilities into the grid. Failure to address these problems will hinder the modernization of the existing power system. In order to build a reliable smart grid, an overview of relevant cyber security and privacy issues is presented. Based on current literatures, several potential research fields are discussed at the end of this paper.
Hydrogen production from water splitting by photo/photoelectron‐catalytic process is a promising route to solve both fossil fuel depletion and environmental pollution at the same time. Titanium dioxide (TiO2) nanotubes have attracted much interest due to their large specific surface area and highly ordered structure, which has led to promising potential applications in photocatalytic degradation, photoreduction of CO2, water splitting, supercapacitors, dye‐sensitized solar cells, lithium‐ion batteries and biomedical devices. Nanotubes can be fabricated via facile hydrothermal method, solvothermal method, template technique and electrochemical anodic oxidation. In this report, we provide a comprehensive review on recent progress of the synthesis and modification of TiO2 nanotubes to be used for photo/photoelectro‐catalytic water splitting. The future development of TiO2 nanotubes is also discussed.
With the advances of power electronic technology, direct-driven permanent magnet synchronous generators (PMSGs) have increasingly drawn the interest of wind turbine manufacturers. At the present time, a commercial PMSG wind turbine primarily makes use of a passive rectifier followed by an insulated gate bipolar transistor (IGBT) inverter. Although a PMSG wind turbine with two back-to-back voltage source IGBT converters is considered more efficient, it has not been widely adopted by the wind power industry. This paper investigates both the conventional and a novel vector control mechanism for a PMSG wind turbine that has two side-by-side voltage source pulsewidth modulation converters. The proposed approach is based on a directcurrent vector control mechanism for control of both machineand grid-side converters of a PMSG wind turbine. Then, an optimal control strategy is developed for integrated control of PMSG maximum power extraction, reactive power, and grid voltage support controls. A transient system simulation using SimPowerSystem is built to investigate the performance of the conventional and proposed control techniques for the PMSG wind turbine under steady and gusty wind conditions. This paper shows that when using the direct-current vector control structure, a PMSG system has excellent performance in various aspects.Index Terms-DC-link voltage control, direct-current vector control, grid voltage support control, maximum wind power extraction, optimal control, permanent magnet synchronous generator (PMSG) wind turbine, reactive power control, voltage source converter (VSC).
Polysaccharide is an abundant and reproducible natural material that is biocompatible and biodegradable. Polysaccharide and its derivatives also possess distinctive properties such as hydrophilicity, mechanical stability, as well as tunable functionality. Polysaccharide‐based hydrogels can be constructed via the physical and/or chemical crosslinking of polysaccharide derivatives with different functional molecules, as porous network structures or nanofibrillar structures. This review discusses the biomedical applications of polysaccharide‐based hydrogels containing native polysaccharides, polysaccharide derivatives, and polysaccharide‐composite hydrogels. Recent works on the fabrication, physical properties, advanced engineering, biomedical applications of cellulose‐, chitosan‐, alginate‐, and starch‐based hydrogels are also elaborated. Such porous swelling scaffolds exhibit great advantages at the interface of a negative pressure system such as wound dressing. In addition, the authors also discuss and summarize the exemplary research works of these hydrogels in the applications of drug release, wound dressing, and tissue engineering. Finally, challenges and future perspectives about the development of polysaccharide‐based hydrogels are discussed.
We propose a simple approach to broadband generation of orbital angular momentum (OAM) carrying vector beams based on compact metamaterials. It consists of two concentric rings in a gold film, where each ring is composed of subwavelength rectangular apertures with gradually varied orientation. The subwavelength rectangular aperture serves as a localized spatial polarizer. We show the generation of different OAM-carrying vector beams with OAM charge number and polarization order varying from -3 to +3 using a 11.2×11.2 μm device. The extinction ratio can exceed 20 dB, and the operation bandwidth (1500 nm) can cover from 1000 to 2500 nm (from near-infrared to mid-infrared). The device provides three degrees of freedom (polarization order l, polarization of input beam σ, and initial orientation angle α(0)) to flexibly generate different OAM-carrying vector beams. We can use a single device to generate two OAM-carrying vector beams with opposite charge sign of OAM by simply controlling the polarization of the input beam. We further study the performance dependence of the designed metamaterials on the offset of the initial orientation angle, length, and width of the rectangular apertures. The obtained results indicate favorable fabrication tolerance.
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