Spontaneous imbibition is significantly influenced by rock wettability, and it has been extensively studied in core-based experiments and numerical simulations owing to its important role in the development of oil/gas reservoir. Due to the fine pore structure and complex wettability of tight sandstone, an in-depth exploration of the effects of wettability on the pore-scale flow physics during spontaneous imbibition is of great value to complement traditional experimental studies and enhance the understanding of microscopic flow mechanisms during the development of tight oil reservoirs. Based on a X-ray computed tomography scanning experiment and a lattice Boltzmann multiphase model, in this work, we systematically investigate the effects of different hydrophilic strengths on the evolution of the imbibition fronts within the micropores and the degree of nonwetting fluid recovery during spontaneous imbibition of tight sandstone. The results show that the wettability significantly affects the morphological characteristics of the imbibition fronts. Under strong hydrophilic conditions, the wetting fluid preferentially invades the pore corner in the form of angular flow. As the contact angle increases, the hysteresis effect at the main terminal interface decreases, and the two-phase interface becomes regular and compact. Wettability also significantly affects the imbibition rate and the nonwetting fluid recovery degree. The smaller the contact angle, the faster the imbibition rate and the higher the recovery degree of nonwetting fluids during the cocurrent spontaneous imbibition.

γ-Al2O3 nanosheets supported rhodium catalysts with Rh loadings between 0.05 and 2 wt% were prepared by impregnation method and used for dry reforming of methane (DRM). It was found that...

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Photocatalytic water splitting for hydrogen production is an effective way to solve energy crisis. However, the challenge of how to solve the problem of short exciton lifetime of the catalyst still remains. In this work, a g-C3N4/UNiMOF/NiS2 (GUN) ternary heterojunction (TH) has been successfully constructed using two-dimensional (2D) UNiMOF as a precursor by the partial hydrothermal sulfidation method. As expected, the optimized GUN-40 heterojunction containing 40 mg of UNiMOF (GUN-40) exhibited higher H2 evolution (572 μmol h–1 g–1) and a longer exciton recombination lifetime (τ = 12.12 ns) than those of pure g-C3N4 (0.67 μmol h–1 g–1, 7.87 ns) under visible light. In addition, the apparent quantum yield (AQY) of GUN-40 was up to 1.54 % at 450 nm. Apparently, the GUN TH structure effectively promotes electron transfer to the NiS2 active site, allowing a long recombination lifetime, and reduces the probability of recombination of electron holes, thus obviously improving photocatalytic efficiency. This work provides insights into the preparation of a cocatalyst using 2D MOF as a template and construction of the TH structure with good charge separation for efficient photocatalysis.

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Background: Cranial radiotherapy is clinically used in the treatment of brain tumours; however, the consequent cognitive and emotional dysfunctions seriously impair the life quality of patients. LW-AFC, an active fraction combination extracted from classical traditional Chinese medicine prescription Liuwei Dihuang decoction, can improve cognitive and emotional dysfunctions in many animal models; however, the protective effect of LW-AFC on cranial irradiation–induced cognitive and emotional dysfunctions has not been reported. Recent studies indicate that impairment of adult hippocampal neurogenesis (AHN) and alterations of the neurogenic microenvironment in the hippocampus constitute critical factors in cognitive and emotional dysfunctions following cranial irradiation. Here, our research further investigated the potential protective effects and mechanisms of LW-AFC on cranial irradiation–induced cognitive and emotional dysfunctions in mice.Methods: LW-AFC (1.6 g/kg) was intragastrically administered to mice for 14 days before cranial irradiation (7 Gy γ-ray). AHN was examined by quantifying the number of proliferative neural stem cells and immature neurons in the dorsal and ventral hippocampus. The contextual fear conditioning test, open field test, and tail suspension test were used to assess cognitive and emotional functions in mice. To detect the change of the neurogenic microenvironment, colorimetry and multiplex bead analysis were performed to measure the level of oxidative stress, neurotrophic and growth factors, and inflammation in the hippocampus.Results: LW-AFC exerted beneficial effects on the contextual fear memory, anxiety behaviour, and depression behaviour in irradiated mice. Moreover, LW-AFC increased the number of proliferative neural stem cells and immature neurons in the dorsal hippocampus, displaying a regional specificity of neurogenic response. For the neurogenic microenvironment, LW-AFC significantly increased the contents of superoxide dismutase, glutathione peroxidase, glutathione, and catalase and decreased the content of malondialdehyde in the hippocampus of irradiated mice, accompanied by the increase in brain-derived neurotrophic factor, insulin-like growth factor-1, and interleukin-4 content. Together, LW-AFC improved cognitive and emotional dysfunctions, promoted AHN preferentially in the dorsal hippocampus, and ameliorated disturbance in the neurogenic microenvironment in irradiated mice.Conclusion: LW-AFC ameliorates cranial irradiation–induced cognitive and emotional dysfunctions, and the underlying mechanisms are mediated by promoting AHN in the dorsal hippocampus and improving the neurogenic microenvironment. LW-AFC might be a promising therapeutic agent to treat cognitive and emotional dysfunctions in patients receiving cranial radiotherapy.