High performance polymer, Polyether Ether Ketone (PEEK) (service temperature À250C to þ300 C, tensile strength: 120 MPa) is gaining significant interest in aerospace and automotive industries. In this investigation, attention is given to understand adhesion properties of PEEK, when surface of the PEEK is modified by two different plasma processes (i) atmospheric pressure plasma and (ii) low pressure plasma under DC Glow Discharge. The PEEK sheets are fabricated by ultra high temperature resistant epoxy adhesive (DURALCO 4703, service temperature À260 C to þ350 C). The surface of the PEEK is modified through atmospheric pressure plasma with 30 and 60 s of exposure and low pressure plasma with 30, 60, 120, 240, and 480 s of exposure. It is observed that polar component of surface energy leading to total surface energy of the polymer increases significantly when exposed to atmospheric pressure plasma. In the case of low pressure plasma, polar component of surface energy leading to total surface energy of the polymer increases with time of exposure up to 120 s and thereafter, it deteriorates with increasing time of exposure. The fractured surface of the adhesively bonded PEEK is examined under SEM. It is observed that unmodified PEEK fails essentially from the adhesive to PEEK interface resulting in low adhesive bond strength. In the case of surface modified PEEK under atmospheric pressure plasma, the failure is entirely from the PEEK and essentially tensile failure at the end of the overlap resulting in significant increase in adhesive bond strength.
Abstract-In this work, the effect of low pressure plasma and atmospheric pressure plasma treatment on sur face properties and adhesion characteristics of high performance polymer, Polyether Ether Ketone (PEEK) are investigated in terms of Fourier Transform Infrared Spectroscopy (FTIR), X ray photoelectron spectros copy (XPS), and Atomic Force Microscopy (AFM). The experimental results show that the PEEK surface treated by atmospheric pressure plasma lead to an increase in the polar component of the surface energy, resulting in improving the adhesion characteristics of the PEEK/Epoxy adhesive system. Also, the roughness of the treated surfaces is largely increased as confirmed by AFM observation. These results can be explained by the fact that the atmospheric pressure plasma treatment of PEEK surface yields several oxygen function alities on hydrophobic surface, which play an important role in increasing the surface polarity, wettability, and the adhesion characteristics of the PEEK/Epoxy adhesive system.
The present investigation aims to optimize the process parameters of Direct Current (DC) and Radio Frequency (RF) glow discharge treatment through air in terms of discharge power and time of exposure for the surface modification of high-density polyethylene (HDPE) sheet, for attaining best adhesive joint of the polymer to mild steel. In order to estimate the extent of surface modification, the surface energies of the polymer surfaces exposed to glow discharge have been determined by measuring contact angles using two standard test liquids of known surface energies. It is observed that at a given power level of DC glow discharge, surface energy and its polar component increase with increasing exposure time, attaining a maximum and then decreasing. In the case of RF glow discharge, surface energy and its polar component increase with increasing exposure time and then saturate. Surface modification by DC glow discharge increases the surface energy of HDPE relatively more at a lower power compared to that observed for RF glow discharge. The dispersion component of surface energy remains almost unaffected. The surfaces have also been studied by electron spectroscopy for chemical analysis (ESCA) and energy-dispersive spectra (EDS). A significant oxygen peak is observed for surface-modified polymer as detected by ESCA and EDS. Lap shear tensile test of an adhesive (Araldite AY 105) joint of HDPE with mild steel has been carried out in optimizing the parameters of DC and RF glow discharge for maximum joint strength. When HDPE is exposed to DC glow discharge, improvement of adhesive joint strength of HDPE to mild steel is found to be by a factor more than 7. On the other hand, when HDPE is exposed to RF glow discharge, results in improvement of adhesive joint strength of HDPE to mild steel by a factor nearer to 7 are found. Thus, DC glow discharge is more capable for increasing wetting and adhesion characteristics of the polymer.
This investigation highlights different surface functionalization processes of multi-walled carbon nanotubes (MWCNTs) and their effects on mechanical properties of polyetherimide nanocomposite. Surfaces of MWCNTs were modified by chemical process and by low-pressure plasma process. There is a significant change in physicochemical characteristics of MWCNTs after chemical and low plasma treatment evident from scanning electron microscopy, transmission electron microscopy, and X-ray photoelectron spectroscopy studies. Due to surface modification of CNTs, there is a significant change in surface morphology and increase in oxygen functionalities such as C=O, C–O, and COOH especially evident in low-pressure plasma treatment; however, differential scanning calorimeter and thermogravimetric analysis studies reveal that thermal properties of the composite do not alter as such. There is a significant increase in mechanical properties of high-performance polymeric nanocomposites when surface-functionalized MWCNTs are dispersed in polymeric matrix; however, surface characteristics of the composite remain almost unchanged evident from contact angle and surface energy studies.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.