High‐entropy alloys (HEAs) and metallic glasses (MGs) are two material classes based on the massive mixing of multiple‐principal elements. HEAs are single or multiphase crystalline solid solutions with high ductility. MGs with amorphous structure have superior strength but usually poor ductility. Here, the stacking fault energy in the high‐entropy nanotwinned crystalline phase and the glass‐forming‐ability in the MG phase of the same material are controlled, realizing a novel nanocomposite with near theoretical yield strength (G/24, where G is the shear modulus of a material) and homogeneous plastic strain above 45% in compression. The mutually compatible flow behavior of the MG phase and the dislocation flux in the crystals enable homogeneous plastic co‐deformation of the two regions. This crystal–glass high‐entropy nanocomposite design concept provides a new approach to developing advanced materials with an outstanding combination of strength and ductility.
This paper describes the observed and the predicted performance of a full·scale trial embankment built to failure on a soft Malaysian marine clay. Predictions of the subsoil deformation, the critical height of fill and the corresponding slip surface are made and subsequently compared to the field measurements. It is of importance to realize that all the predictions were made prior to the actual failure of the embankment. The comparison with measurements was possible only after the International Symposium on Trial Embankments on Malaysian Marine Clays, was held in Kuala Lumpur, Malaysia, in November 1989, during which the field data were made available to the invited predictors (including the second writer) by the Malaysian Highway Authority. Finite-element codes based on the modified Cam-clay theory (CRISP) and hyperbolic stress-strain model (ISBILD) were utilized to investigate the behavior of the embankment and the foundation soil until failure. The type of numerical modeling includes purely undrained, fully drained, and a coupled consolidation analysis. The finite-element solutions are subsequently compared with the conventional stability analy.sis.
The stereology, variant distribution and coarsening behavior of semicoherent α(hcp) precipitates in a β(bcc) matrix of a Ti5553 alloy has been analyzed, and a dominant 3-variant cluster has been observed in which the variants are related to each other by an axis-angle pair <11 0> 60 ᴼ. Shape and spatial distribution independent elastic self and interaction energies for all pairwise and triplet combinations of α have been calculated and it is found that the 3-cluster combination that is experimentally observed most frequently has the lowest energy for the semicoherent state. The coarsening behavior of the delta distribution follows LSW kinetics after an initial transient, and has been modeled by phase field methods.
When metals are mechanically loaded at elevated temperatures for extended periods of time, creep damage will occur in the form of cavities at grain boundaries. In the present experiments it is demonstrated that in binary iron-tungsten alloys creep damage can be self healed by selective precipitation of a W-rich phase inside these cavities. Using synchrotron X-ray nano-tomography the simultaneous evolution of creep cavitation and precipitation is visualized in 3D images with a resolution down to 30 nm. The degree of filling by precipitation is analysed for a large collection of individual creep cavities. Two clearly different types of behaviour are observed for isolated and linked cavities, where the isolated cavities can be filled completely, while the linked cavities continue to grow. The demonstrated selfhealing potential of tungsten in iron-based metal alloys provides a new perspective on the role of W in high-temperature creep-resistant steels.
Millions worldwide suffer from arthritis of the hips, and total hip replacement is a clinically successful treatment for end‐stage arthritis patients. Typical hip implants incorporate a cobalt alloy (Co–Cr–Mo) femoral head fixed on a titanium alloy (Ti‐6Al‐4V) femoral stem via a Morse taper junction. However, fretting and corrosion at this junction can cause release of wear particles and metal ions from the metallic implant, leading to local and systemic toxicity in patients. This study is a multiscale structural‐chemical investigation, ranging from the micrometer down to the atomic scale, of the underlying mechanisms leading to metal ion release from such taper junctions. Correlative transmission electron microscopy and atom probe tomography reveals microstructural and compositional alterations in the subsurface of the titanium alloy subjected to in vitro gross‐slip fretting against the cobalt alloy. Even though the cobalt alloy is comparatively more wear‐resistant, changes in the titanium alloy promote tribocorrosion and subsequent degradation of the cobalt alloy. These observations regarding the concurrent occurrence of electrochemical and tribological phenomena are vital to further improve the design and performance of taper junctions in similar environments.
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