A new route consisting of simultaneous centrifugal spinning and solution blowing to form polymer nanofibers is reported. The fiber diameter (60–1000 nm) is shown to be a function of polymer concentration, rotational speed, and working pressure of the processing system. The fiber length is dependent on the rotational speed. The process can deliver 6 kg of fiber per hour and therefore offers mass production capabilities compared with other established polymer nanofiber generation methods such as electrospinning, centrifugal spinning, and blowing.
Highly stretchable and highly resilient polymer-clay nanocomposite hydrogels were synthesized by in situ polymerization of acrylamide in the presence of pristine montmorillonite (MMT) or chitosan-treated MMT nanoplatelets at an elevated temperature. Both nanocomposite hydrogels can be stretched to a strain of no less than 1290%. The treatment of clay with chitosan improves the tensile strength, elongation at break, and energy at break of the nanocomposite hydrogel by 237%, 102%, and 389%, respectively, due to the strong chitosan-MMT electrostatic interaction and the grafting of polyacrylamide onto chitosan chains. Both hydrogels display excellent resilience with low hysteresis; with a maximum tensile strain of 50%, ultralow hysteresis is found, while, with a maximum strain of 500%, both hydrogels fully recover their original state in just 1 min. The superb resilience of the nanocomposite hydrogels is attributed to the strong interactions within the hydrogels brought by chain branching, multiple hydrogen bonding, covalent bonding, and/or electrostatic force. The hydrogels can be fabricated into different shapes and forms, including microfibers spun using pressurized gyration, which may find a variety of potential applications in particular in healthcare.
In this work we aim to synthesize biocompatible ZnO nanoparticles from the zinc nitrate via green process using leaf extracts of the Costus pictus D. Don medicinal plant. FTIR studies confirm the presence of biomolecules and metal oxides. X-ray diffraction (XRD) structural analysis reveals the formation of pure hexagonal phase structures of ZnO nanoparticles. The surface morphologies of ZnO nanoparticles observed under a scanning electron microscope (SEM) suggest that most ZnO crystallites are hexagonal. EDX analysis confirms the presence of primarily zinc and oxygen. TEM images show that biosynthesized zinc oxide nanoparticles are hexagonal and spherical. The plausible formation mechanisms of zinc oxide nanoparticles are also predicted. The biosynthesized zinc oxide nanoparticles exhibit strong antimicrobial behavior against bacterial and fungal species when employing the agar diffusion method. Synthesized ZnO nanoparticles exhibit anticancer activity against Daltons lymphoma ascites (DLA) cells as well as antimicrobial activity against some bacterial and fungal strains.
A one-pot single-step novel process has been developed to form microbubbles up to 250 μm in diameter using a pressurized rotating device. The microbubble diameter is shown to be a function of rotational speed and working pressure of the processing system, and a modified Rayleigh-Plesset equation has been derived to explain the bubble-forming mechanism. A parametric plot is constructed to identify a rotating speed and working pressure regime, which allows for continuous bubbling. Bare protein (lysozyme) microbubbles generated in this way exhibit a morphological change, resulting in microcapsules over a period of time. Microbubbles prepared with gold nanoparticles at the bubble surface showed greater stability over a time period and retained the same morphology. The functionalization of microbubbles with gold nanoparticles also rendered optical tunability and has promising applications in imaging, biosensing, and diagnostics.
A simple and efficient solution mixing method has been developed for the synthesis of the G-V2O5 nanocomposite. By this method, one-dimensional V2O5 rods are decorated onto the two-dimensional graphene sheets. The synthesized nanocomposites are characterized by XRD, SEM with elemental mapping, TEM, FT-IR, Raman, BET, and XPS analyses. The photocatalytic activity of the G-V2O5 nanocomposite studied with methylene blue dye shows strong degradation efficiency with direct sunlight irradiation compared to UV and visible light sources. The mechanism of methylene blue dye degradation by the G-V2O5 nanocomposite has been elucidated through the kinetics of the degradation process by calculating the rate constant and half-life time of the degradation process.
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