Without pure water, it is impossible to survive for any living beings. The ratio of freshwater on our planet is very poor and the demand is increasing with time for the growing population. Furthermore, water is being contaminated by industrial and agricultural activities, pharmaceuticals, technocratic civilization, pesticides, garments, global changes etc. In addition to this, environmental pollution and global warming are swelling due to the greenhouse and harmful gases generated from the dumping and burning of fossil fuel. Addressing these problems, it is necessary to find out the cost-effective and environmental friendly processes to purify the contaminated water and air. Activated carbons (ACs) are one of the best solutions for removing the pollutants from aqueous and atmosphere as it is the carbonaceous materials with a high degree of porosity, well-developed surface area, and distinguished functional groups which are required for elimination of contaminants. The preparations of activated carbon are easy and safe processes, mainly from the pyrolysis or gasification of biomass with heat and/or chemicals. The recycling and regeneration of activated carbon after use are also essential for resource maintenance and environmental safety. Thus, AC can protect the ecosystem in a double direction by purifying the water and air from the pollutants.
Pennisetum purpureum is one of the most invasive perennial grasses of the Poaceae family, which are abundant in southeast Asia including Brunei Darussalam. The pyrolysis process at a slow heating rate proved to be highly promising for biochar production. The production and characterization of different Pennisetum purpureum biochars have been investigated at the pyrolysis temperatures of 400 °C, 500 °C and 600 °C with a heating and nitrogen flow rate of 5 °C/min and 0.5 L/min, respectively. The observed higher heating values were 22.18 MJ/kg, 23.02 MJ/kg, 23.75 MJ/kg, and the alkaline pH were 9.10, 9.86, 10.17 for the biochar at 400 °C, 500 °C, 600 °C temperatures, respectively. The water holding capacity was one hundred percent for all biochars and continued to increase for higher pyrolysis temperature. SEM images show that the porosity of the biochars has been enhanced with increased temperatures due to the rearrangement of crystallinity and aromaticity. On the other hand, the yields of biochar have been decreased from 35.13% to 23.02% for the increase of pyrolysis temperature from 400 °C to 600 °C. Energy dispersive X-ray analysis shows that the O/C atomic ratios were 0.15, 0.08 and 0.06 for the biochar of 400, 500 and 600 °C which validates the improvement in heating values. FT-IR analysis revealed that the available functional groups in the biochars were CO , C=C, and C-H. Thermogravimetric analysis (TGA) under pyrolysis condition showed residue of 46.56%, 51.13% and 55.67% from the biochar at 400, 500, and 600 °C, respectively. The derivative thermogravimetry (DTG) graph indicates that the degradation rate is higher for 400 °C biochar than the 600 °C biochar.
To support the global restart of elective surgery, data from an international prospective cohort study of 8492 patients (69 countries) was analysed using artificial intelligence (machine learning techniques) to develop a predictive score for mortality in surgical patients with SARS-CoV-2. We found that patient rather than operation factors were the best predictors and used these to create the COVIDsurg Mortality Score (https://covidsurgrisk.app). Our data demonstrates that it is safe to restart a wide range of surgical services for selected patients.
Hydrogen is a free, limitless, and environmentally friendly resource. To enhance the production performance of hydrogen by photocatalytic water splitting, its preparation and application was investigated using carbon-based materials (graphene, graphite, carbon nanotubes, activated carbon). Photocatalytic hydrogen processing is among the most promising strategies for ensuring long-term energy stability and preventing further environmental degradation. The selection of co-catalysts and sacrificial agents to support the main catalyst is crucial for increasing hydrogen production. Several analyses were conducted to examine the characteristics as well as the use of various parameters to determine how carbonaceous materials would improve hydrogen production.
Activated carbon (AC) is an extremely porous carbonaceous adsorptive substance which has a rigid carbon matrix with high surface area and broad functional groups. The structure is connected by chemical bonds; arranged irregularly, generating a highly porous arrangement of corners, crevices, claps, and cracks between the carbon layers. Activated carbons are produced high-temperature and chemical activation of waste biomass. The pores in the lattice network of activated carbon permit the removal of impurities from gaseous and liquid medium through adsorption. At present, the COVID-19 disease is the prime concern around the whole world because of its exponential infections and death rate. There is no medicine for this virus, and protection is the only remedy to survive from this contagious disease. Using a face mask is one of the best methods to get rid of COVID-19. The mask combined with activated carbon can be beneficial for adsorbing and disinfecting the virus as it is the versatile adsorbent for the elimination of the organic, inorganic, and pathogenic contaminants.
Protonic ceramic fuel cells (PCFCs) have become the most efficient, clean and cost-effective electrochemical energy conversion devices in recent years. While significant progress has been made in developing proton conducting electrolyte materials, mechanical strength and durability still need to be improved for efficient applications. We report that adding 5 mol% Zn to the Y-doped barium cerate-zirconate perovskite electrolyte material can significantly improve the sintering properties, mechanical strength, durability and performance. Using same proton conducting material in anodes, electrolytes and cathodes to make a strong structural backbone shows clear advantages in mechanical strength over other arrangements with different materials. Rietveld analysis of the X-ray and neutron diffraction data of BaCe0.7Zr0.1Y0.15Zn0.05O3−δ (BCZYZn05) revealed a pure orthorhombic structure belonging to the Pbnm space group. Structural and electrochemical analyses indicate highly dense and high proton conductivity at intermediate temperature (400–700 °C). The anode-supported single cell, NiO-BCZYZn05|BCZYZn05|BSCF-BCZYZn05, demonstrates a peak power density of 872 mW cm−2 at 700 °C which is one of the highest power density in an all-protonic solid oxide fuel cell. This observation represents an important step towards commercially viable SOFC technology.
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