Electrolyte additives have been explored to attain significant breakthroughs in the long-term cycling performance of lithium-ion batteries (LIBs) without sacrificing energy density; this has been achieved through the development of stable electrode interfacial structures and the elimination of reactive substances. Here we highlight the potential and the challenges raised by studies on electrolyte additives toward addressing the interfacially induced deterioration of high-capacity electrodes with a focus on Ni-rich layered oxides and Si, which are expected to satisfy the growing demands for high-energy-density batteries. We also discuss issues with the design of electrolyte additives for practical viability. A deep understanding of the roles of existing electrolyte additives depending on their functional groups will aid in the design of functional additive moieties capable of building robust interfacial layers, scavenging undesired reactive species, and suppressing the gas generation that causes safety hazards and shortened lifetimes of LIBs.

New insight into the effect of fluorine doping and oxygen vacancies on electrochemical performance of Co 2 MnO 4 for flexible quasi-solid-state asymmetric supercapacitors, Energy Storage Materials (2019),

Solid electrolyte interphases generated using electrolyte additives are key for anode-electrolyte interactions and for enhancing the lithium-ion battery lifespan. Classical solid electrolyte interphase additives, such as vinylene carbonate and fluoroethylene carbonate, have limited potential for simultaneously achieving a long lifespan and fast chargeability in high-energy-density lithium-ion batteries (LIBs). Here we report a next-generation synthetic additive approach that allows to form a highly stable electrode-electrolyte interface architecture from fluorinated and silylated electrolyte additives; it endures the lithiation-induced volume expansion of Si-embedded anodes and provides ion channels for facile Li-ion transport while protecting the Ni-rich LiNi0.8Co0.1Mn0.1O2 cathodes. The retrosynthetically designed solid electrolyte interphase-forming additives, 5-methyl-4-((trifluoromethoxy)methyl)-1,3-dioxol-2-one and 5-methyl-4-((trimethylsilyloxy)methyl)-1,3-dioxol-2-one, provide spatial flexibility to the vinylene carbonate-derived solid electrolyte interphase via polymeric propagation with the vinyl group of vinylene carbonate. The interface architecture from the synthesized vinylene carbonate-type additive enables high-energy-density LIBs with 81.5% capacity retention after 400 cycles at 1 C and fast charging capability (1.9% capacity fading after 100 cycles at 3 C).

Dermal and inhalation exposure of the applicator to the insecticide fenavalerate in an apple orchard was measured for risk assessment during treatment. Emulsifiable concentrate (EC) and wettable powder (WP) formulations were sprayed using a speed sprayer (SS) or power sprayer (PS). Dermal patches, gloves, socks, and masks were used to monitor potential dermal exposure to fenavalerate, while personal air samplers with XAD-2 resins were used to monitor potential inhalation exposure. Validation of analytical methods was performed for the instruments' limit of detection, limit of quantitation, reproducibility, linearity of calibration curve, and recovery of fenvelerate from various exposure matrices. The results were encouraging and reasonable for an exposure study. Applicability of XAD-2 resin was evaluated with a trapping efficiency and breakthrough test. During mixing/loading, the amount of dermal exposure ranged from 262.8 μg (EC/SS) to 1652.6 μg (WP/PS) of fenvalerate, corresponding to ~0.0011-0.0066% of the total prepared quantity. In the case of WP, the amount of dermal exposure was 2032.3 μg (0.0081% of the total applied amount) for SS and 1087.9 μg (0.0145%) for PS after application. In the case of EC, the amount of dermal exposure was 3804.6 μg (0.0152%) for SS and 4055.0 μg (0.0541%) for PS after application. The primary body parts subject to exposure were thigh and upper arm for SS, and thigh and hand for PS. The amount of inhalation exposure with WP was 2.2 μg (8.65 × 10⁻⁶% of the total applied amount) for SS and 1.3 g (1.67 × 10⁻⁵%) for PS. The amount of inhalation exposure with EC was 2.5 μg (9.81 × 10⁻⁶%) for SS and 3.7 μg (4.97 × 10⁻⁵%) for PS. The absorbable quantity of exposure and margin of safety (MOS) were calculated for risk assessment. The MOS for all 4 cases was much greater than 1, indicating a low possibility of risk.

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Two-dimensional (2D) layered materials-based p-n diode is an essential element in the modern semiconductor industry for facilitating the miniaturization and structural flexibility of devices with high efficiency for future optoelectronic...

The introduction of a trimethylsilyl (TMS) motif in electrolyte additives for lithium-ion batteries is regarded as an effectual approach to remove corrosive hydrofluoric acid (HF) that structurally and compositionally damages the electrode−electrolyte interface and gives rise to transition metal dissolution from the cathode. Herein, we present that electrolyte additives with TMS moieties lead to continued capacity loss of polycrystalline (PC)-LiNi 0.8 Co 0.1 Mn 0.1 O 2 (NCM811) cathodes coupled with graphite anodes compared to additives without TMS as the cycle progresses. Through a comparative study using electrolyte additives with and without TMS moieties, it is revealed that the TMS group is prone to react with residual lithium compounds, in particular, lithium hydroxide (LiOH) on the PC-NCM811 cathode, and the resulting TMS-OH triggers the decomposition of PF 5 created by the autocatalytic decomposition of LiPF 6 that generates reactive species, namely, HF and POF 3 . This work aims to offer a way to build favorable interface structures for Ni-rich cathodes covered with residual lithium compounds through a study to figure out the roles of TMS moieties of electrolyte additives.

This study aimed to analyze the demographic characteristics and health behaviors related to chronic diseases and to identify factors that may affect chronic diseases. Data from the Seventh Korea National Health and Nutrition Examination Survey were used, and 3795 adults aged above 40 years were included. The following demographic variables were obtained: sex, age, education, income, type of health insurance, and private insurance. The following health behavior factors were also analyzed: medical checkup, drinking, smoking, exercise, obesity, and hypercholesterolemia. Participants with lower socioeconomic status had a higher risk of developing chronic diseases. Meanwhile, those with private health insurance had a lower risk of developing chronic diseases. In addition, participants who underwent medical checkups and performed exercises had a lower risk, while those with obesity and hypercholesterolemia had a higher risk of developing chronic diseases. It is necessary to manage chronic diseases through comprehensive programs, rather than managing these diseases individually, and through community primary care institutions to improve health behaviors.