In this study, the hybrid corona-dielectric barrier discharge plasma treatment was employed to modify the physical, chemical and morphological characteristics of a half-knitted fabric composed of 92% polyamide 6.6 and 8% elastane (PA). These properties of the fabric were evaluated by the water contact angle, x-ray diffraction, infrared spectroscopy, scanning electron microscopy and atomic force microscopy techniques. In addition, the dyeing and washing processes were also investigated. A significant reduction of the contact angle was observed for plasma-treated PA. Infrared spectroscopy analyses indicated that C-H, N-H, and NO groups in PA increased after plasma treatment, explaining the improved coloring strength for the plasma-treated samples when dyed with reactive and acid dyes. A better fixation of dye was also observed after the atmospheric plasma treatment. Furthermore, dyeing with a basic and acid dye caused the dyeability increases for the plasma-treated sample compared with the untreated sample.
This paper presents a review, analysis and classification about 3D printing. Through the CAPES Sucupira platform, 124 articles with a high degree of relevance published between the years 2014 and 2018 were selected. Each of these articles was classified by means of 9 categories: study types, affiliation, approach, origin of the study, geographic scope, unit of analysis, scope, benefits and negative points. Through the results obtained, it was verified that the number of articles on 3D printing is increasing every year, which indicates its i mportance and popularity. Most of the time, scientific research is conducted and led by people connected to universities in Europe, Asia and the Americas. And finally, the number of citations related to the benefits of 3D printing are greater than the number of citations on the negative points of the process.
The garment industry demands stamping processes that are increasingly more agile and less damaging to the environment. In this scenario, digital printing, with the sublimation transfer printing technique, presents itself as a viable option for synthetic textile substrates. Among the synthetic fibres, polyamide (P.A.) fibres stand out, as they are light, soft, durable, and boast moderate sweat absorption; however, before sublimation, superficial treatment is necessary in order to present good results such as withstanding washing and maintaining colour intensity. This study addresses the surface modification of the PA6.6 textile substrate by activating non-thermal plasma at atmospheric pressure to receive dye through the sublimation method with dispersed dye. The knitted PA6.6 fabric surface treatment was performed with plasma application at atmospheric pressure using air in the Plasmatreater AS400 equipment. The sublimation transfer effects were evaluated by wash fastness and colourimetric tests. To assess the wettability effect of the control and treated samples, a contact angle test was carried out on PA6.6 samples. Fourier transform infrared spectroscopy (FTIR) proved the changes in chemical functional groups in the fibres. The results showed a decrease in the contact angle of the textile surface, 4–5 grayscale results for colour change and transfer for washing, and an increase in colour strength. In the FTIR tests, there is an increase in the transmittance value of aromatic, carboxylic groups (C=O, 580 cm−1), amides (N=H, 1630 cm−1), and methyl groups (CH 1369 to 1463 cm−1) as well as the presence of new functional groups in the 3064 cm−1 and 2860 cm−1 bands. These conditions allowed sublimation in the knitted PA6.6 fabric and showed increased colour strength and good wash fastness.
A abordagem do sistema energético nacional como um sistema sociotécnico é fundamental para fomentar o diálogo dessa questão com a sociedade. A partir de uma metodologia do tipo exploratória, foi construída uma hipótese sob a ótica do conceito de reverso saliente proposto por Thomas Hughes. Foram apresentadas relações complexas de interdependência entre aspectos físicos e técnicos, sociais, ambientais, econômicos e políticos, onde a cada mudança de padrão de elementos todos os demais precisam se adaptar para buscar o equilíbrio do sistema. Foi possível identificar pontos de aderência entre os conceitos propostos por Hughes e o sistema energético nacional. A partir da análise da tendência de crescimento da demanda de energia, a mudança nos padrões de consumo da sociedade e a estagnação da distribuição das fontes de energia nacionais, evidencia-se a produção energia como um reverso saliente no contexto sociotécnico brasileiro e alerta-se para as necessidades de mudanças estruturais para reversão deste gargalo nacional.
A mathematical model capable of providing a forecast of future consumption and import of natural gas is essential for the planning of the Brazilian energy matrix. The aim of this study is to compare three mathematical models, logistic model or model of Verhulst, exponential model or the model of Malthus and the model of von Bertalanffy to analyze the possibilities of these models to describe the evolution of production, import and consumption of natural gas in Brazil, from data provided by the energy balance of the Ministry of Mines and Energy (MME) from 1970 to 2009. A projection of the production and the import of natural gas up to 2017 is made with the models studied in this article and compared with the Brazilian Ten-Year Plan for Expansion of Energy (PDE). At the end of this paper a comparison with the Hubbert model for Brazilian natural gas production is made. These data were adjusted to use the differential equations which describe the models of population growth. All the computer work used in this article: graphics, resolution of differential equations, calculations of linearization and the least squares fitting was prepared in the software MatLab. The results obtained by means of graphs show that the population dynamics models (logistic, exponential and von Bertalanffy) can be applied in modeling the production, import and consumption of natural gas in Brazil.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.