This study has demonstrated that a wide variety of organic compounds, including esters, aldehydes, ketones, alcohols, and hydrocarbons, adsorb on stable, anhydrous «-lactose. The heats of adsorption of these compounds on stable, anhydrous a-lactose have been determined by the gas chromatographic method, and are taken as indications of the strengths of adsorption. On this basis it has been established that for a given
Benzo[c]cinnolin‐bis‐[tricarbonyl‐Fe] (I) reagiert mit Phosphinen oder anderen weichen Lewisbasen abhängig vom Liganden und den Reaktionsbedingungen zu den di‐ und monosubstituierten Derivaten (IIa) bzw. (IIb).
Mechanismus und Kinetik der thermischen Substitution eines CO‐Liganden im Di‐u‐phosphido‐Fe‐Komplex (I), dem photochemischen Reaktionsprodukt von Nonacarbonyldieisen und Diphenylphosphin, durch Phosphin oder Phosphit‐Liganden unter Bildung der Monosubstitutionsprodukte (II) werden untersucht, Aktivierungsparameter ermittelt und diskutiert.
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