ChemInform Abstract: MECHANISMS OF SUBSTITUTION OF LIGAND‐BRIDGED DIIRON HEXACARBONYL COMPLEXES. BIS(μ‐DIPHENYLPHOSPHIDE)‐BIS(TRICARBONYLIRON). PROMOTION OF AN SN1 MECHANISM BY A BULKY BRIDGING LIGAND
Abstract:Mechanismus und Kinetik der thermischen Substitution eines CO‐Liganden im Di‐u‐phosphido‐Fe‐Komplex (I), dem photochemischen Reaktionsprodukt von Nonacarbonyldieisen und Diphenylphosphin, durch Phosphin oder Phosphit‐Liganden unter Bildung der Monosubstitutionsprodukte (II) werden untersucht, Aktivierungsparameter ermittelt und diskutiert.
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