Atmospheric-pressure microplasma-assisted electrochemistry was used to synthesize Ag nanoparticles (NPs) for plasmonic applications. It is shown that the size and dispersion of the nanoparticles can be controlled by variation of the microplasma-assisted electrochemical process parameters such as electrolyte concentration and temperature. Moreover, Ag NP synthesis is also achieved in the absence of a stabilizer, with additional control over the dispersion and NP formation possible. As the microplasma directly reduces Ag ions in solution, the incorporation of toxic reducing agents into the electrolytic solution is unnecessary, making this an environmentally friendly fabrication technique with strong potential for the design and growth of plasmonic nanostructures for a variety of applications. These experiments therefore link microplasma-assisted electrochemical synthesis parameters with plasmonic characteristics.
Tunable synthesis of bimetallic Au(x)Ag(1-x) alloyed nanoparticles and in situ monitoring of their plasmonic responses is presented. This is a new conceptual approach based on green and energy efficient, reactive, and highly-non-equilibrium microplasma chemistry.
This paper is the second in a series looking at understanding the factors controlling and predicting marine aerosol concentration on land. It looks at results from three transects across the Australian continent. In each transect, the airborne salinity was measured, using the wet candle method at distances from 10 m to 40 -300 km from the coast. The positions of the transects were selected to give a signi cant variation in the factors controlling salt production and transport. For example, one transect in South Australia was established where both high whitecap activity is likely to promote salt production and at terrain and prevailing winds are likely to favour transport. Another, in Queensland, was established where calm seas will limit salt production and very seasonal winds and high relative humidity and rainfall will limit transport. On the basis of this experimental study, the general validity of the fundamental concepts put forward in Part 1 is assessed. Further, the feasibility of building a mathematical model to predict salinity is determined and the main factors causing variations in salinity on land are outlined. The results are then used to assist in the interpretation of previous work in the literature. CEST/2058 The authors are with CSIRO Manufacturing and Infrastructure Technologies,
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