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Twelve new organotin(IV) complexes of the type RnSnLm [where n = 3, m = 1, R = CH3 or C6H5; n = 2, m = 2, R = C6H5 or C4H9 ; L = anion of Schiff bases derived from the condensation of 2-amino-5-(o-anisyl)-l,3,4-thiadiazole with salicylaldehyde (HL-1), 2- hydroxynaphthaldehyde (HL-2) and 2-hydroxyacetophenone (HL-3)] have been synthesized and characterized by elemental analysis, molar conductances, electronic, infrared, far-infrared, 1H NMR and 119Sn Mössbauer spectral studies. Thermal studies of two complexes, viz., Ph3Sn (L-1) and Ph2Sn(L-2)2 have been carried out in the temperature range 25-1000∘C using TG, DTG and DTA techniques. All these complexes decompose gradually with the formation of SnO2 as an end product. In vitro antimicrobial activity of the Schiff bases and their complexes has also been determined against Streptococcus faecalis, Klebsiella pneumoniae, Escherichia coli, Pseudomonas aeruginosa, Staphylococcus aureus Penicillin resistance (2500 units), Candida albicans, Cryptococcus neoformans, Sporotrichum schenckii, Trichophyton mentagrophytes and Aspergillus fumigatus. The Schiff bases (HL-1), (HL-2) and the organotin(IV) compounds have also been tested against various important herbicidal, fungicidal, insecticidal species and also for parasitological activity against freeliving nematode.

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Some new organotin(IV) complexes of the general formula, RnSnCl4−n·L [where n = 3, R = CH3 or C6H5; n = 2, R = C6H5; L = Schiff bases derived from the condensation of 2-amino-5-(o-methoxyphenyl)-1,3,4-thiadiazole with salicylaldehyde (L-1), 2-hydroxy-1-naphthaldehyde (L-2), 2′-hydroxyacetophenone (L-3), benzyl methyl ketone (L-4), acetylacetone (L-5), and 2-furancarbaldehyde (L-6)] have been synthesized and characterized by elemental analyses, molar conductances, electronic, infrared, far-infrared, 1H and 119Sn NMR and Mössbauer spectral studies. Thermal studies of three complexes, viz., Ph3SnCl(L-2), Me3SnCl(L-4), and Ph3SnCl(L-5) have been carried out in the temperature range 25—1000 °C using TG, DTG, and DTA techniques. All these complexes decompose gradually with the formation of SnO2 as an end product. In vitro antimicrobial activity of the ligands and their complexes has also been determined against Streptococcus faecalis, Klebsiella pneumoniae, Escherichia coli, Pseudomonas aeruginosa, Staphylococcus aureus Penicillin resistance (2500 units), Candida albicans, Cryptococcus neoformans, Sporotrichum schenckii, Trichophyton mentagrophytes, and Aspergillus fumigatus.

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New organotin(1V) complexes of the types. R,SnL,, [where n = 3, m = 1, R = C,H,. CI-I, or C4119; n = 2, m = 2 . R = C,H, or C,H, and L = anion of N-acetylglycine (HL') and ~-acetyl-i)i.-tryptophan (HL')]. (R,Sn),L' [where R = C,H,, CH, or C,H, and L' = anion of N-acetyl-i--cysteine (H2L3)], R$nL'[where R = C,H, or C4H9 and L' = anion of (H2L3)] and Bu,(L)SnOSn(L)Bu, [where L = anion of (HL')] have been synthesized and characterized by elemental analyses, molar conductance. electronic. infrared, far-infrared, 'H NMR, I3C NMR and "' Sn Miissbauer spectral studies. Thermal studies of three complexes have been carried out in the temperature range 18-1O0O0 C using TG, DTG and DTA techniques. Possible structures of the complexes have also been proposed.

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