One major objective of the European Joint Research Project "Traceability for surface spectral solar ultraviolet (UV) radiation" was to reduce the uncertainty of spectral UV measurements. The measurement instrument used for this work was the portable UV European reference spectroradiometer Qasume. The calibration uncertainty of this instrument was decreased and validated by a comparison of direct calibrations against a primary standard for spectral irradiance, a high temperature blackbody radiator, and against a reference detector using a spectrally tunable laser as a monochromatic source. The spectral irradiance responsivity of the reference detector is traceable to the primary standard of optical power, realized through a cryogenic radiometer, and to the SI unit of meter. The measuring technique was improved by the construction of a new reference spectroradiometer, QasumeII. An improved input optics removes the dependences of the measured solar irradiance on the angle of incident for solar zenith angle smaller than 75 deg. Moreover, a hybrid photon detection system enables continuous tracking of the instrument's responsivity changes. For both spectroradiometer systems an uncertainty budget was calculated. The improvements have reduced the measurement uncertainties of solar spectral UV irradiance measurements from 4.8% in 2005 to 2.0% (k=2) in the spectral region above 310 nm. The largest sources of uncertainty were the absolute spectral irradiance responsivity calibration, the angular response uncertainty, and the instrument stability using the hybrid detector, which were reduced from 3.6% to 1.1%, from 1.2% to 0.6%, and from 0.65% to 0.4%, with respect to the situation prior to the project. The new instrument was validated during a four month intercomparison relative to the Qasume reference. The mean ratio of the solar irradiance scans between the two reference spectroradiometers has an offset of +0.7% and a standard deviation of ±1.5% for a wavelength greater than 305 nm, which is well within the combined uncertainty of 3.7% calculated from the uncertainties of the two systems.

Gonioreflectometric determination of reflectance factors that involves hemispherical collection of reflected flux, which is an alternative to integrating sphere-based methods, is discussed. A detailed description of a gonioreflectometer built at the Helsinki University of Technology is presented. The instrument is used to establish an absolute scale of total diffuse reflectance factors throughout the spectral range 360-830 nm. The hemispherical reflectance factors are obtained through integration of the gonioreflectometric measurement results. The reflectance factors of white high-quality artifacts can be determined with a combined standard uncertainty of 0.20%. Results of test measurements were found to be in agreement with values traceable to other absolute scales based on integrating-sphere methods.

A method of measuring the absolute spectral irradiance of quartz-halogen-tungsten lamps is described, based on the known responsivity of a filter radiometer, the components of which are separately characterized. The characterization is described for the wide wavelength range essential for deriving the spectrum of a lamp, from 260 nm to 950 nm. Novel methods of interpolation and measurement are implemented for the spectral responsivity of the filter radiometer. The combined standard uncertainty of spectral irradiance measurements is less than 1.4 parts in 10 2 from 290 nm to 320 nm (ultraviolet B) and 4 parts in 10 3 from 440 nm to 900 nm (visible to near-infrared). As an example, the derived spectral irradiances of two lamps measured at the Helsinki University of Technology (HUT, Finland) are presented and compared with the measurement results of the National Institute of Standards and Technology (NIST, USA) and the Physikalisch-Technische Bundesanstalt (PTB, Germany). The comparisons indicate that the HUT spectral irradiance scale is between those of the NIST and the PTB in the wavelength range 290 nm to 900 nm. The long-term reproducibility of the spectral irradiance measurements is also presented. Over a period of two years, the reproducibility appears to be better than 1 part in 10 2 .

Abstract. Three reference Dobsons (regional standard Dobsons No. 064, Germany and No. 074, Czech Republic as well as the world standard No. 083, USA) were optically characterized at the Physikalisch-Technische Bundesanstalt (PTB) in Braunschweig in 2015 and at the Czech Metrology Institute (CMI) in Prague in 2016 within the EMRP ENV 059 project “Traceability for atmospheric total column ozone”. Slit functions and the related parameters of the instruments were measured and compared with G. M. B. Dobson's specifications in his handbook. All Dobsons show a predominantly good match of the slit functions and the peak (centroid) wavelengths with deviations between −0.11 and +0.12 nm and differences of the full width half maximum (FWHM) between 0.13 and 0.37 nm compared to the nominal values at the shorter wavelengths. Slightly larger deviations of the FWHMs from the nominal Dobson data, up to 1.22 nm, can be seen at the longer wavelengths, especially for the slit function of the long D-wavelength. However, differences between the effective absorption coefficients (EACs) for ozone derived using Dobson's nominal values of the optical parameters on one hand and these measured values on the other hand are not too large in the case of both “old” Bass–Paur (BP) and “new” IUP-ozone (Institut für Umweltphysik, University of Bremen) absorption cross sections. Their inclusion in the calculation of the total ozone column (TOC) leads to improvements of significantly less than ±1 % at the AD-wavelengths between −1 and −2 % at the CD-wavelengths pairs in the BP-scale. The effect on the TOC in the IUP-scale is somewhat larger at the AD-wavelengths, up to +1 % (D074), and smaller at the CD-wavelengths pair, from −0.44 to −1.5 %. Beside this positive effect gained from the data with higher metrological quality that is needed for trend analyses and satellite validation, it will be also possible to explain uncommon behaviours of field Dobsons during calibration services, especially when a newly developed transportable device TuPS (tuneable portable radiation source) from CMI proves its capability to provide similar results as the stationary setups in the laboratories of National Metrology Institutes. Then, the field Dobsons can be optically characterized as well during regular calibration campaigns. A corresponding publication will be prepared using the results of TuPS-based measurements of more than 10 Dobsons in field campaigns in 2017.

An approach is presented to characterize and correct stray light in spectra measured with array spectroradiometers and caused by out-of-spectral range radiation. A prerequisite for out-of-range stray light correction is knowledge of the spectral irradiance not measured by the instrument itself. A way of solving this problem for solar UV measurements is shown. The effect of out-of-range stray light is especially important for solar UV spectroradiometers typically having a spectral range narrower than that of the silicon detectors in use. Two different types of instruments used for solar UV measurements were characterized and corrected for out-of-range and in-range stray light. As a hardware solution to the out-of-range stray light problem, a bandpass filter was fitted in one array spectroradiometer. Results of test measurements using this modified instrument are also shown.