Bentonite buffers at temperatures beyond 100 °C could reduce the amount of high-level radioactive waste in a deep geological repository. However, it is necessary to demonstrate that the buffer surrounding the canisters withstands such elevated temperatures, while maintaining its safety functions (regarding long-term performance). For this reason, an experiment with thermal loading of bentonite powder at 150 °C was arranged. The paper presents changes that the Czech Mg/Ca bentonite underwent during heating for one year. These changes were examined by X-ray diffraction (XRD), thermal analysis with evolved gas analysis (TA-EGA), aqueous leachates, Cs sorption, cation exchange capacity (CEC), specific surface area (SSA), free swelling, saturated hydraulic conductivity, water retention curves (WRC), quantitative polymerase chain reaction (qPCR), and next-generation sequencing (NGS). It was concluded that montmorillonite was partially altered, in terms of the magnitude of the surface charge density of montmorillonite particles, based on the measurement interpretations of CEC, SSA, and Cs sorption. Montmorillonite alteration towards low- or non-swelling clay structures corresponded well to significantly lower swelling ability and water uptake ability, and higher saturated hydraulic conductivity of thermally loaded samples. Microbial survivability decreased with the thermal loading time, but it was not completely diminished, even in samples heated for one year.
The main petrographic variables of intrusive rocks that influence the technical test methods common used within the aggregate industry were identified and evaluated, the aim being to investigate whether petrographic description could be used as a tool for the preliminary quality evaluation of different rock groups. Evaluation of the dependence of the technical test methods on petrographic variables covered 26 intrusive rocks, including some of their altered varieties (orthogneisses), divided into two groups: 17 granitoids and 9 gabbroids. The selective designated samples were analysed to determine their petrographic characteristics and resistance to fragmentation, wear and wear by abrasion from studded tyres. In order to identify the complicated associations between the petrographic and technical properties, multivariate statistical evaluation was performed. The results of statistical evaluation highlighted that mean grain size of mica minerals, grain size distribution, content of mica minerals and mean grain size were the main variables influencing the technical properties of granitoid rocks, while for gabbroid rocks, the main influences were the frequency of microcracks, mica content, grain size distribution and mean grain size.
The alkali silica reaction (ASR), which originates in highly alkaline conditions in concrete where reactive forms of silica are available, causes serious damage to concrete structures. The ASR potential of various quartz-rich aggregates (pegmatite quartz, quartzite, quartz meta-greywacke, and chert) was quantified using accelerated mortar bar test (AMBT), chemical test (CT), and scanning electron microscopy combined with petrographic image analysis (SEM-PIA). Only two samples (quartz meta-greywacke, and pegmatite quartz) were judged as deleterious according to the CT; the other aggregates were classified as innocuous. AMBT gave different results. Quartz meta-greywacke, chert, and quartzite exceeded the 0.100 % expansion limit after 14 days of testing. Pegmatite quartz indicated a lower value. The results of SEM-PIA confirmed the results of AMBT, indicating the most extensive ASR in those AMBs containing chert and quartz meta-greywacke. Parts of aggregates were leached out and massive deposits of alkali-silica gels were found filling air voids, microcracks, and the aggregate/cement paste interface. The medium or low degree of ASR was confirmed in AMBs containing quartzite or pegmatite quartz, respectively. ASR accentuated pre-existing microcracks and formed new dissolution gaps. In contrast, no correlation was found with the results of CT, which under-evaluated the ASR potential of chert and quartzite and over evaluated the ASR potential of pegmatite quartz. The variable ASR potential of the investigated aggregates was explained by the significant content of poorly crystalline matrix (in chert and quartz meta-greywacke), and by the presence of strained quartz typical with undulose extinction and the origin of quartz subgrains (in quartzite and pegmatite quartz).
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