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Herein, we report the synthesis of Au nanoparticles (AuNPs) in chitosan (CTS) solution by chemically reducing HAuCl4. CTS was further functionalized with glycidyl methacrylate (chitosan-g-glycidyl methacrylate/AuNP, CTS-g-GMA/AuNP) to improve the mechanical properties for cellular regeneration requirements of CTS-g-GMA/AuNP. Our nanocomposites promote excellent cellular viability and have a positive effect on cytokine regulation in the inflammatory and anti-inflammatory response of skin cells. After 40 days of nanocomposite exposure to a skin wound, we showed that our films have a greater skin wound healing capacity than a commercial film (TheraForm®), and the presence of the collagen allows better cosmetic ave aspects in skin regeneration in comparison with a nanocomposite with an absence of this protein. Electrical percolation phenomena in such nanocomposites were used as guiding tools for the best nanocomposite performance. Our results suggest that chitosan-based Au nanocomposites show great potential for skin wound repair.

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Sargassum spp. affects the Caribbean shores; thus, its remotion or valorization is a priority. This work aimed to synthesize a low-cost magnetically retrievable Hg+2 adsorbent functionalized with ethylenediaminetetraacetic acid (EDTA) based on Sargassum. The Sargassum was solubilized to synthesize by co-precipitation a magnetic composite. A central composite design was assessed to maximize the adsorption of Hg+2. The solids yield magnetically attracted mass, and the saturation magnetizations of the functionalized composite were 60.1 ± 17.2%, 75.9 ± 6.6%, and 1.4 emu g−1. The functionalized magnetic composite yielded 29.8 ± 0.75 mg Hg+2 g−1 of chemisorption after 12 h, pH 5, and 25 °C achieving 75% Hg+2 adsorption after four reuse cycles. Crosslinking and functionalization with Fe3O4 and EDTA created differences in surface roughness as well as the thermal events of the composites. The Fe3O4@Sargassum@EDTA composite was a magnetically recovered biosorbent of Hg2+.

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