Sargassum@magnetite Composite EDTA-Functionalized for the Potential Removal of Mercury

Abstract

Sargassum spp. affects the Caribbean shores; thus, its remotion or valorization is a priority. This work aimed to synthesize a low-cost magnetically retrievable Hg+2 adsorbent functionalized with ethylenediaminetetraacetic acid (EDTA) based on Sargassum. The Sargassum was solubilized to synthesize by co-precipitation a magnetic composite. A central composite design was assessed to maximize the adsorption of Hg+2. The solids yield magnetically attracted mass, and the saturation magnetizations of the functionalized composite were 60.1 ± 17.2%, 75.9 ± 6.6%, and 1.4 emu g−1. The functionalized magnetic composite yielded 29.8 ± 0.75 mg Hg+2 g−1 of chemisorption after 12 h, pH 5, and 25 °C achieving 75% Hg+2 adsorption after four reuse cycles. Crosslinking and functionalization with Fe3O4 and EDTA created differences in surface roughness as well as the thermal events of the composites. The Fe3O4@Sargassum@EDTA composite was a magnetically recovered biosorbent of Hg2+.

Synthesis, Characterization, and Application of EDTA-Coated Maghemite Magnetic Nanoparticles for Oil Spill Cleanup from Water Surface

“…Many studies have shown that ethylene diamine tetraacetic acid (EDTA) has a strong affinity for iron oxide nanoparticles, which might make it easier for colloids to spread out, lower high surface energy, and stop nanoparticles from sticking together (41)(42)(43)(44).…”