The remarkable mechanical, electrical, and thermal capabilities of monolayer graphene make it a wonder substance. As the number of layers in graphene flakes increases to few-layer graphene (number of layers ≤ 5) and multi-layer graphene (number of layers ≤ 10), its properties are affected. In order to obtain the necessary qualities, it is crucial to manage the number of layers in the graphene flake. Therefore, in the current review, we discuss the various processes for producing mono- and few-/multi-layer graphene. The impact of mono-/few-/multi-layer graphene is then assessed with regard to its qualities (including mechanical, thermal, and optical properties). Graphene possesses unique electrical features, such as good carrier mobility, typical ambipolar behaviour, and a unique energy band structure, which might be employed in field effect transistors (FETs) and utilized in radio frequency (RF) circuits, sensors, memory, and other applications. In this review, we cover graphene’s integration into devices for biomolecule detection as well as biomedical applications. The advantages of using graphene in each situation are explored, and samples of the most cutting-edge solutions for biomedical devices and other applications are documented and reviewed.
In this work, we report the synthesis of a magnetically recoverable catalyst through immobilizing copper (II) over the Fe3O4@SiO2 nanoparticles (NPs) surface [Fe3O4@SiO2-L–Cu(II)] (L = pyridine-4-carbaldehyde thiosemicarbazide). Accordingly, synthesized catalysts were determined and characterized by energy dispersive X-ray spectrometry (EDS), X-ray diffraction (XRD), Fourier transforms infrared spectroscopy (FT-IR), vibrating sample magnetometer (VSM), field emission scanning electron microscopy (FESEM), and thermogravimetric-differential thermal analysis (TG-DTA) procedures. The [Fe3O4@SiO2-L–Cu(II)] was used for the reduction of Cr(VI), 4-nitrophenol (4-NP) and organic dyes such as Congo Red (CR) and methylene blue (MB) in aqueous media. Catalytic performance studies showed that the [Fe3O4@SiO2–L–Cu(II)] has excellent activity toward reduction reactions under mild conditions. Remarkable attributes of this method are high efficiency, removal of a homogeneous catalyst, easy recovery from the reaction mixture, and uncomplicated route. The amount of activity in this catalytic system was almost constant after several stages of recovery and reuse. The results show that the catalyst was easily separated and retained 83% of its efficiency after five cycles without considerable loss of activity and stability.
Bone and periodontium are tissues that have a unique capacity to repair from harm. However, replacing or regrowing missing tissues is not always effective, and it becomes more difficult as the defect grows larger. Because of aging and the increased prevalence of debilitating disorders such as diabetes, there is a considerable increase in demand for orthopedic and periodontal surgical operations, and successful techniques for tissue regeneration are still required. Even with significant limitations, such as quantity and the need for a donor area, autogenous bone grafts remain the best solution. Topical administration methods integrate osteoconductive biomaterial and osteoinductive chemicals as hormones as alternative options. This is a promising method for removing the need for autogenous bone transplantation. Furthermore, despite enormous investigation, there is currently no single approach that can reproduce all the physiologic activities of autogenous bone transplants. The localized bioengineering technique uses biomaterials to administer different hormones to capitalize on the host’s regeneration capacity and capability, as well as resemble intrinsic therapy. The current study adds to the comprehension of the principle of hormone redirection and its local administration in both bone and periodontal tissue engineering.
A finite-volume method based on the OpenFOAM is used to numerically study the factors affecting the migration of viscoelastic droplets on rigid surfaces with wettability gradients. Parameters investigated include droplet size, relaxation time, solvent viscosity, and polymer viscosity of the liquid comprising droplets. The wettability gradient is imposed numerically by assuming a linear change in the contact angle along the substrate. As reported previously for Newtonian droplets, the wettability gradient induces spontaneous migration from hydrophobic to hydrophilic region on the substrate. The migration of viscoelastic droplets reveals the increase in the migration speed and distance with the increase in the Weissenberg number. The increase in droplet size also shows the increase in both the migration speed and distance. The increase in polymer viscosity exhibits the increase in migration speed but the decrease in migration distance.
The effects of surface wettability and viscoelasticity on the dynamics of liquid droplets under an electric field are studied experimentally. A needle-plate electrode system is used as the power source to polarize a dielectric plate by the corona discharge emitted at the needle electrode, creating a new type of steerable electric field realized. The dynamics of droplets between the dielectric plate and a conductive substrate include three different phenomena: equilibrium to a stationary shape on substrates with higher wettability, deformation to form a bridge between the top acrylic plate and take-off on the substrates with lower wettability. Viscoelastic droplets differ from water in the liquid bridge and takeoff phenomena in that thin liquid filaments appear in viscoelastic droplets, not observed for Newtonian droplets. The equilibrated droplet exhibits more pronounced heights for Newtonian droplets compared to viscoelastic droplets, with a decrease in height with the increase in the concentration of the elastic constituent in the aqueous solution. In the take-off phenomenon, the time required for the droplet to contact the upper plate decreases with the concentration of the elastic constituent increases. It is also found that the critical voltage required for the take-off phenomenon to occur decreases as the elasticity increases.
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