Photoelectrochemical cells based on oxotitanylphthalocyanine (TiOPc) films and an I(3)(-)/I(-) redox couple have been constructed. The TiOPc films were prepared on an indium-tin oxide coated glass plate (ITO) by the micellar disruption method and characterized by their unique nanoporous structure. A photocurrent action spectrum for input radiation directed through the ITO/TiOPc film, film-thickness dependence, and morphological investigation revealed that the cells consisted of a bulk heterojunction formed between the nanoporous TiOPc films and the liquid I3-/I- electrolyte, resulting in a larger short-circuit current (J(sc)= 2.1 mA/cm(2)), open-circuit voltage (V(oc)= 0.11 V), fill factor (ff= 0.31), and hence a larger energy conversion efficiency (eta= 0.13% for an incident white-light intensity of 53 mW/cm2) than the bilayer structure composed of the vaccum-evaporated TiOPc compact film and the I(3)(-)/I(-) electrolyte (J(sc)= 0.16 mA/cm(2), V(oc)= 0.018 V, ff = 0.27, and eta = (1.5 x 10(-3)%).
The objective of this study was to investigate the optimal shapes and arrangements of sinkers attached to net cages to prevent their deformation in a current. A series of model experiments were conducted in a circulating water channel, using 5 different types of sinker(high-weighted ball, low-weighted ball, columntype, egg-shaped and iron bar-framed) and 2 types of square net cage constructed from both Nylon Raschel netting and Nylon knotted netting, on a 1/20th scale. The deflection of the model nets against the flow was smallest with the iron bar-framed weight compared to the other four types of sinker. It was expected that the optimal shapes of sinkers would be either the ball or egg-shape; however, iron bar-framed weight actually had larger drag forces. The dispersed deployment of sinkers on the bottom frames of model net cages performed better with relatively slow flows, while the concentrated deployment at 4 corners functioned better with relatively fast flows, in preventing the nets from becoming severely deformed. The deformation of the net cages was larger for the Nylon knotted netting than the Nylon Raschel netting. With respect to flow resistance, the Nylon Raschel netting, rather than the Nylon knotted netting, was more suitable for construction of net cages.
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