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CuI–Y zeolite catalysts, which are robust and recyclable, assisted by TEMPO catalyses quantitatively the aerobic oxidation of a wide range of benzylic alcohols into aldehydes in ethanol under mild conditions without additional additives.

Robust core–shell magnetic materials catalyse quantitatively the aerobic oxidation of a wide range of benzylic alcohols into corresponding aldehydes at room temperature showing excellent tolerance towards the substituents on the phenyl ring.

The development of environmental dealings for the green synthesis of metal nanoparticle using plant mediated process is evolving an important branch of nano biotechnology. It offers a controlled synthesis of metal nanoparticles with welldefined shape, size, composition and morphology. The present study reveals the green synthesis of gold nanoparticle that is non-toxic, novel and eco-friendly. This synthesis approach is cost effective, eco-friendly and promising method for generation of new materials which can be used for many potential applications in field of science and medical. The colour change in UV-visible spectroscopy at absorption peak of 536 nm occurred due to the surface Plasmon Resonance effect. The antimicrobial activity and mechanism of gold nanoparticles studies for the bacterial growth of gram-negative bacteria like E.coli, Pseudomonas aeruginosa and gram-positive bacteria like Bacillus subtilis respectively. Highly crystalline nanoparticles of size 10nm are confirmed from HR-TEM which supports with d spacing of XRD analysis. Further the characteristics of the obtained gold nanoparticles were studied using XRD, UV-Vis spectroscopy, Scanning Electron Microscopic, and High Resolution Transmission Electron microscopy and the results are presented in detail.

The vibrational assignments of the observed wavenumbers have been made by analyzing the infrared and Raman spectra of L-valinium picrate in the crystalline state at room temperature. L-Valinium acts as the cation of the crystal and the carbonyl C O group exists in the protonated form in it. Asymmetric deformation and symmetric deformation modes of the isopropyl group have been identified, indicating that the two CH 3 groups are in different environments. The stretching and bending modes of the various functional groups have been shifted owing to the extensive intermolecular hydrogen bonding in the crystal. The symmetry of the picrate anion has not been modified in the crystal by the hydrogen bonding with the cation. Fermi resonance is also observed.

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