In recent years, alloy and alloy-ceramic coatings have gained a considerable attention owing to their favorable physicochemical and technological properties. In this review, we investigate Ni, NiCo alloy and NiCo–ceramic composite coatings prepared by electrodeposition. Electrodeposition is a versatile tool and cost-effective electrochemical method used to produce high quality metal coatings. Surface finish and tribological properties of the coatings can be further improved by the addition of suitable agents and control of deposition operating conditions. In this review, Ni, NiCo alloy and NiCo–ceramic composite coatings prepared by electrodeposition are reviewed by critically evaluating previous researches. The use of the coatings and their potential for future research and development are discussed.
Ni–W/Cr2O3 nanocomposite coatings were synthesized from aqueous sulphate-citrate electrolyte containing Cr2O3 nanoparticles on a steel surface using conventional electrodeposition technique. This study was aimed at investigating the influence of Cr2O3 nanoparticle content on the microstructure, corrosion resistance, and mechanical properties of electrodeposited Ni–W/Cr2O3 nanocomposite coatings. Ni–W binary alloy coatings were deposited and optimized before addition of the nanoparticles to produce high-quality coatings. The microstructure and chemical composition of the Ni–W/Cr2O3 nanocomposite coatings were evaluated using scanning electron microscope (SEM), energy dispersive X-ray spectrometer (EDS), and XRD. Corrosion resistance properties were evaluated using potentiodynamic polarization (Tafel) measurements in 3.5 wt.% NaCl medium. The corrosion resistance and microhardness are significantly higher in Ni–W/Cr2O3 nanocomposite coatings compared to pure Ni–W binary alloy and increase with the increase in content of Cr2O3 nanoparticles in the coatings. Wear resistance is also higher in Ni–W/Cr2O3 nanocomposite coatings.
High velocity arc spraying was used to prepare FeCrAl/Al composite coating on Q235 steel substrate by simultaneously spraying FeCrAl wire as the anode and Al wire as the cathode. The composite coating was sprayed with varying voltage and current to obtain optimum coating characteristics. FeCrAl coating was also prepared for comparison purposes. The surface microstructure of the coatings was characterized by scanning electron microscope (SEM) and X-ray diffraction (XRD). The average microhardness of the coatings and the substrate was analyzed and compared. Corrosion resistance was investigated by means of electrochemical tests. The image results showed that a lamellar structure consisted of interwoven layers of FeCrAl and Al. Al and FeCr constituted the main phases with traces of oxides and AlFe intermetallic compounds. The average porosity was reduced and microhardness of the coatings was improved with increasing voltage and current. The FeCrAl/Al coating formed alternating layers of hard and ductile phases; the corrosion resistance of the coatings in the sodium chloride (NaCl) solution depended on the increase in Al content and spray parameters. The corrosion resistance tests indicated that FeCrAl/Al coating had a better corrosion resistance than the FeCrAl coating. FeCrAl/Al can be used to coat steel substrates and increase their corrosion resistance.
In view of the low seeding efficiency and precision of seeders used for Brassica chinensis in China, a new double-row pneumatic precision metering device for Brassica chinensis was designed, fabricated, and evaluated. With the characteristics of small size and high sphericity of Brassica chinensis seeds in mind, the structure and key dimensions of the metering plate were determined, and a force analysis of the seed-filling process was carried out. The negative pressure (NP), angular velocity (AV) of the metering plate, and cone angle (CA) of the suction hole were selected as the main influencing factors of the experiment. In order to explore the influence of each single factor and the interaction between factors on the seeding performance, a single factor experiment and a central composite design (CCD) experiment were designed, respectively, and the experimental results were analyzed by analysis of variance (ANOVA). After optimizing the main influencing factors such that the target of the qualified index (QI) was greater than 94% and the miss index (MI) was less than 2.5%, it was found that when CA was 60°, NP was 1.55–1.72 kPa, and AV was 1.1–1.9 rad/s, the seeding performance was excellent. The bench verification results of seeding performance (94% ≤ Q ≤ 100%, 0 ≤ M ≤ 2.5%) and the coefficient of variation (CV) of seed mass (CV of seed mass in outer and inner circle: 5.15%; CV of total seed mass: 8.60%) under the condition of parameter optimization were analyzed; as a result, the accuracy of the parameter optimization was confirmed.
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